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Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine

A light-promoted methodology for the iodotrifluoromethylation of alkenes was developed. For the first time a Togni reagent was exploited as the source of both the CF3 group and iodine atom. Preliminary mechanistic studies suggest that both CF3I and 2-iodobenzoic acid are direct sources of the iodine atom that is tr

Autoren:   Redouane Beniazza; Maxime Douarre; Dominique Lastécouères; Jean-Marc Vincent
Journal:   Chemical Communication
DOI:   10.1039/C7CC00214A
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