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Size and shape effects on the thermodynamic properties of nanoscale volumes of water

Small systems are known to deviate from the classical thermodynamic description, among other things due to their large surface area to volume ratio compared to corresponding big systems. As a consequence, extensive thermodynamic properties are no longer proportional to the volume, but are instead higher order funct

Autoren:   Bjørn A. Strøm; Jean-Marc Simon; Sondre K. Schnell; Signe Kjelstrup; Jianying He; Dick Bedeaux
Journal:   Physical Chemistry Chemical Physics
DOI:   10.1039/C7CP00874K
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