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Mixed-Valence Metallogrid [CoIII2CoII2] with Unusual Electronic Structure and Single-Ion-Magnet Characterization

The mixed-valence metallogrid [Co4(L-2H)4(CH3CO2)2 (CH3OH)2]∙Et2O (1) has been theoretically and experimentally analyzed to assign the valence and spin state. HF-EPR reveals the presence of axial anisotropy (D = -34.4 cm-1) with a significant transverse component (E = 9.5 cm-1). Slow magnetic relaxation effe

Autoren:   Dayu Wu; Wei Huang; Feifei Pan; Zhenxing Wang; Zhongwen Ouyang; XueJun Feng; Jiande Gu; Yan Bai
Journal:   Dalton Transactions
DOI:   10.1039/C7DT00564D
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