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Theoretical study of complexes formed between cations and curved aromatic systems: electrostatics does not always control cation-[small pi] interaction

The present work studies the interaction of two extended curved π-systems (corannulene and sumanene) with various cations (sodium, potassium, ammonium, tetramethylammonium, guanidinium and imidazolium). The polyatomic cations are models of groups found in important biomolecules in which the cation-π interact

Autoren:   Jorge A. Carrazana-García; Enrique M. Cabaleiro-Lago; Jesus Rodriguez-Otero
Journal:   Physical Chemistry Chemical Physics
DOI:   10.1039/C7CP01491K
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