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Asymmetric Three-Component Inverse Electron-Demand Aza-Diels-Alder Reaction: Efficient Synthesis of Ring-Fused Tetrahydroquinolines

Diels or no Diels: The titled reaction of aldehydes, anilines, and cyclopentadiene, promoted by 0.5-5 mol % of an N,N[prime]-dioxide-scandium complex, afforded ring-fused tetrahydroquinolines that contained three contiguous stereocenters. The one-pot reaction delivers the products with good yields and excellent diastereo- and enantioselectivities.

Autoren:   Mingsheng Xie, Xiaohong Chen, Yin Zhu, Bo Gao, Lili Lin, Xiaohua Liu, Xiaoming Feng
Journal:   Angewandte Chemie International Edition
Jahrgang:   2010
DOI:   10.1002/anie.201000590
Erscheinungsdatum:   14.04.2010
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