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18.674 Aktuelle Fachpublikationen in Angewandte Chemie

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A diazido mannose analog as a chemoenzymatic synthon for synthesizing di‐N‐acetyllegionaminic acid‐containing glycosides

19.01.2018 | Abhishek Santra, An Xiao, Hai Yu, Wanqing Li, Yanhong Li, Linh Ngo, John B. McArthur, Xi Chen, Angewandte Chemie, 2018

A novel strategy is developed to expand the scope of chemoenzymatic synthetic products by designing a chemoenzymatic synthon. The synthon is enzymatically converted to carbohydrate analogs which are readily derivatized chemically to produce desired targets. The strategy is demonstrated for ...

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Targeting a dark excited state of HIV‐1 nucleocapsid by anti‐retroviral thioesters revealed by NMR

18.01.2018 | Lalit Deshmukh, Vitali Tugarinov, Daniel H. Appella, G. Marius Clore, Angewandte Chemie, 2018

HIV‐1 nucleocapsid (NCp7) is a two Cys2HisCys zinc knuckle (N‐Zn and C‐Zn) protein that plays a key role in viral replication. Here we characterize NCp7 conformational dynamics by NMR relaxation dispersion and chemical exchange saturation transfer measurements. While the N‐Zn knuckle is ...

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Targeting a dark excited state of HIV‐1 nucleocapsid by anti‐retroviral thioesters revealed by NMR

18.01.2018 | Lalit Deshmukh, Vitali Tugarinov, Daniel H. Appella, G. Marius Clore, Angewandte Chemie, 2018

HIV‐1 nucleocapsid (NCp7) is a two Cys2HisCys zinc knuckle (N‐Zn and C‐Zn) protein that plays a key role in viral replication. Here we characterize NCp7 conformational dynamics by NMR relaxation dispersion and chemical exchange saturation transfer measurements. While the N‐Zn knuckle is ...

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Stable and Highly Efficient Electrochemical Production of Formic Acid from Carbon Dioxide Using Diamond Electrodes

18.01.2018 | Keisuke Natsui, Hitomi Iwakawa, Norihito Ikemiya, Kazuya Nakata, Yasuaki Einaga, Angewandte Chemie, 2018

High faradaic efficiencies can be achieved in the production of formic acid (HCOOH) by metal electrodes, such as Sn or Pb, in the electrochemical reduction of carbon dioxide (CO2). However, the stability and environmental load in using them are problematic. Here, we investigated the ...

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MoP Nanoparticles Supported on In‐doped Porous Carbon: Outstanding Catalysts for High‐efficient CO2 Electroreduction

18.01.2018 | Xiaofu Sun, Lu Lu, qinggong Zhu, Congyi Wu, Dexin Yang, Chunjun Chen, Buxing Han, Angewandte Chemie, 2018

Electrochemical reduction of CO2 into value‐added product is an interesting area. In this work, we synthesized MoP nanoparticles supported on porous carbon using metal‐organic frameworks as the carbon precusor, and conducted the first work on CO2 electroreduction using MoP‐based catalyst. It was ...

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Norbert W. Mitzel

18.01.2018 | Angewandte Chemie, 2018

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Photoinduced Pedalo‐Type Motion in an Azodicarboxamide‐Based Molecular Switch

18.01.2018 | Saeed Amirjalayer, Alberto Martinez‐Cuezva, Jose Berna, Sander Woutersen, Wybren Jan Buma, Angewandte Chemie, 2018

Durch Licht gesteuerte molekulare Schalter auf der Grundlage eines Azodicarboxamid‐Chromophors werden von S. Amirjalayer, S. Woutersen, W. J. Buma et al. in ihrer Zuschrift (DOI: 10.1002/ange.201709666) beschrieben. Die pedalartige Schaltung funktioniert wie beim Fahrrad und erfordert nur sehr ...

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Peripheral Templation‐Modulated Interconversion between an A4L6 Tetrahedral Anion Cage and A2L3 Triple Helicate with Guest Capture/Release

18.01.2018 | Xuemin Bai, Chuandong Jia, Yanxia Zhao, Dong Yang, Shi‐Cheng Wang, Anyang Li, Yi‐Tsu Chan, Yao‐Yu Wang, Xiao‐Juan Ya ..., Angewandte Chemie, 2018

Periphere Templatierung wurde genutzt, um einen ungewöhnlichen tetraedrischen A4L6‐Käfig (A=Anion, L=Ligand) zu stabilisieren, über den C. Jia, B. Wu et al. in ihrer Zuschrift berichten (DOI: 10.1002/ange.201712080). Der A4L6‐Käfig kann durch die Einwirkung verschiedener Stimuli (Wechsel des ...

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Ion Specificity on Electric Energy Generated by Flowing Water Droplets

18.01.2018 | Junwoo Park, Suhwan Song, ChaeHo Shin, YoungJun Yang, Stefan A. L. Weber, Eunji Sim, Youn Sang Kim, Angewandte Chemie, 2018

Abstract The development of energy‐conversion devices using water movement has actively progressed. Ionovoltaic devices, which are driven by ion dynamics, show ion specificity by which different ions with identical charges show different output performance. However, the ion specificity remains ...

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Ion Specificity on Electric Energy Generated by Flowing Water Droplets

18.01.2018 | Junwoo Park, Suhwan Song, ChaeHo Shin, YoungJun Yang, Stefan A. L. Weber, Eunji Sim, Youn Sang Kim, Angewandte Chemie, 2018

Abstract The development of energy‐conversion devices using water movement has actively progressed. Ionovoltaic devices, which are driven by ion dynamics, show ion specificity by which different ions with identical charges show different output performance. However, the ion specificity remains ...

mehr

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