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4.542 Aktuelle Fachpublikationen in Chemistry - A European Journal
rss05.04.2013 | Jacob Baggerman, Natalia Haraszkiewicz, Piet G. Wiering, Giulia Fioravanti, Massimo Marcaccio, Francesco Paolucci, E ..., Chemistry - A European Journal, 2013
Abstract Rotaxane molecular shuttles were studied in which a tetralactam macrocyclic ring moves between a succinamide station and a second station in which the structure is varied. Station 2 in all cases is an aromatic imide, which is a poor hydrogen‐bond acceptor in the neutral form, but ...
05.04.2013 | Jie Yang, Liang Zhou, Jun Zhang, Jin Zou, Zhiguo Yuan, Chengzhong Yu, Chemistry - A European Journal, 2013
Abstract The confinement of phosphates inside adsorbents is important for not only entrophication control, but also the recovery of phosphorous, a depleting natural resource. However, the behaviour of chemisorbed phosphates inside nanoporous materials has not been systematically studied. ...
04.04.2013 | Ryota Ueno, Daishi Fujino, Hideki Yorimitsu, Atsuhiro Osuka, Chemistry - A European Journal, 2013
Abstract Triisopropylsilyltetrathiafulvalene (TIPS‐TTF) has been devised as a promising platform for the synthesis of low‐symmetry TTF derivatives. The bulky TIPS group allows TIPS‐TTF to undergo palladium‐catalyzed direct diarylation as well as LDA‐mediated dilithiation exclusively on ...
04.04.2013 | Zoel Codolà, João M. S. Cardoso, Beatriz Royo, Miquel Costas, Julio Lloret‐Fillol, Chemistry - A European Journal, 2013
Abstract Exceptional water oxidation (WO) turnover frequencies (TOF=17 000 h−1), and turnover numbers (TONs) close to 400 000, the largest ever reported for a metal‐catalyzed WO reaction, have been found by using [Cp*IrIII(NHC)Cl2] (in which ...
04.04.2013 | Da‐Young Sung, Jayavant L. Gunjakar, Tae Woo Kim, In Young Kim, Yu Ri Lee, Seong‐Ju Hwang, Chemistry - A European Journal, 2013
Abstract A new prompt room temperature synthetic route to 2D nanostructured metal oxide–graphene‐hybrid electrode materials can be developed by the application of colloidal reduced graphene oxide (RGO) nanosheets as an efficient reaction accelerator for the synthesis of δ‐MnO2 2D ...
04.04.2013 | Yu‐Hua Deng, Jin‐Quan Chen, Long He, Tai‐Ran Kang, Quan‐Zhong Liu, Shi‐Wei Luo, Wei‐Chen Yuan, Chemistry - A European Journal, 2013
Abstract Highly enantioselective cross‐aldol reactions between acetaldehyde and activated acyclic ketones are reported for the first time. Various acyclic ketones, such as saturated and unsaturated keto esters, reacted with acetaldehyde in the presence of a chiral primary amine and a ...
04.04.2013 | Feng Zhou, Marc‐Oliver Simon, Chao‐Jun Li, Chemistry - A European Journal, 2013
Abstract A new strategy for the construction of biaryls by a transition‐metal‐free process is presented. A sequence of a Grignard reaction, dehydration, and oxidative aromatization affords the desired products in a one‐pot fashion. One‐pot biaryl synthesis: An efficient method for ...
28.03.2013 | Xiaochuan Duan, Di Li, Huili Zhang, Jianmin Ma, Wenjun Zheng, Chemistry - A European Journal, 2013
Abstract In the work presented here, well‐dispersed ferric giniite microcrystals with controlled sizes and shapes are solvothermally synthesized from ionic‐liquid precursors by using 1‐n‐butyl‐3‐methylimidazolium dihydrogenphosphate ([Bmim][H2PO4]) as phosphate source. The success of this ...
28.03.2013 | Zheng Wang, Shuai Luo, Shoude Zhang, Wu‐Lin Yang, Yang‐Zi Liu, Honglin Li, Xiaoyan Luo, Wei‐Ping Deng, Chemistry - A European Journal, 2013
Abstract The first catalytic enantioselective 1,3‐dipolar cycloaddition of azomethine ylides to α‐aminoacrylate catalyzed by a AgOAc/ferrocenyl oxazolinylphosphine (FOXAP) system was developed, which exhibits excellent exo‐ and enantioselectivity (92–99 % ee). This process provides ...
28.03.2013 | Patrick Hemberger, Andras Bodi, Thomas Gerber, Max Würtemberger, Udo Radius, Chemistry - A European Journal, 2013
Abstract The photoionization and dissociative photoionization of Im(iPr)2, 1,3‐diisopropylimidazolin‐2‐ylidene, was investigated by imaging photoelectron photoion coincidence (iPEPICO) with vacuum ultraviolet (VUV) synchrotron radiation. A lone‐pair electron of the carbene carbon atom is ...
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