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9.274 Aktuelle Fachpublikationen in Inorganic Chemistry


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Insight into the Am–O Phase Equilibria: A Thermodynamic Study Coupling High-Temperature XRD and CALPHAD Modeling

16.06.2017 | Enrica Epifano; Christine Guéneau; Renaud C. Belin; Romain Vauchy; Florent Lebreton; Jean-Christophe Richaud; Alexis ..., Inorganic Chemistry, 2017

In the frame of minor actinide transmutation, americium can be diluted in UO2 and (U, Pu)O2 fuels burned in fast neutron reactors. The first mandatory step to foresee the influence of Am on the in-reactor behavior of transmutation targets or fuel is to have fundamental knowledge of the Am–O ...


Correction to Bond Fission and Non-Radiative Decay in Iridium(III) Complexes

16.06.2017 | Xiuwen Zhou; Paul L. Burn; Benjamin J. Powell, Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b01260


Concentration-Driven Selectivity of Energy Transfer Channels and Color Tunability in Ba3La(PO4)3:Tb3+, Sm3+ for Warm White LEDs

16.06.2017 | Weijie Zhou; Meng Gu; Yiyi Ou; Caihua Zhang; Xuejie Zhang; Lei Zhou; Hongbin Liang, Inorganic Chemistry, 2017

Here, we report the large-scale emission color tunability in Ba3La(PO4)3:Tb3+, Sm3+ (BLPO:TS) system based on the detailed discussion on the concentration-driven selectivity of energy transfer (ET) channels from Tb3+ to Sm3+. It is induced by the concentration-dependent 5D3 and 5D4 emissions of ...


Bonding Properties of Aluminum Nitride at High Pressure

16.06.2017 | Zhao Liu; Da Li; Shuli Wei; Wenjie Wang; Fubo Tian; Kuo Bao; Defang Duan; Hongyu Yu; Bingbing Liu; Tian Cui, Inorganic Chemistry, 2017

Exploring the bonding properties and polymerization mechanism of stable polymeric nitrogen phases is the main goal of our high-pressure study. The pressure versus composition phase diagram of the Al–N system is established. In addition to the known Fm3̅m phase of AlN, a notable monoclinic phase ...


TQOPEN (N,N,N′,N′-Tetrakis(2-quinolylmethyl)-3-oxa-1,5-pentanediamine) Family as Heptadentate Fluorescent Cd2+ Sensors

16.06.2017 | Yuji Mikata; Asako Kizu; Kana Nozaki; Hideo Konno; Hiroshi Ono; Shunsuke Mizutani; Shin-ichiro Sato, Inorganic Chemistry, 2017

A quinoline-based heptadentate ligand, N,N,N′,N′-tetrakis(2-quinolylmethyl)-3-oxa-1,5-pentanediamine (TQOPEN), exhibits a fluorescence increase (ICd/I0 = 25, ϕCd = 0.017) at 428 nm upon addition of 1 equiv of Cd2+. In contrast, 1 equiv of Zn2+ induces a negligible fluorescence change due to weak ...


Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal–Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?

15.06.2017 | Kwang Soo Lim; Woo Ram Lee; Han Geul Lee; Dong Won Kang; Jeong Hwa Song; Jeremy Hilgar; Jeffrey D. Rinehart; Dohyun ..., Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b00899


Blue-to-Green Emitting Neutral Ir(III) Complexes Bearing Pentafluorosulfanyl Groups: A Combined Experimental and Theoretical Study

14.06.2017 | Amlan K. Pal; Adam F. Henwood; David B. Cordes; Alexandra M. Z. Slawin; Ifor D. W. Samuel; Eli Zysman-Colman, Inorganic Chemistry, 2017

A structure–property relationship study of neutral heteroleptic (1 and 2, [Ir(C∧N)2(L∧X)]) and homoleptic (3 and 4, fac-[Ir(C∧N)3]) Ir(III) complexes (where L∧X = anionic 2,2,6,6-tetramethylheptane-3,5-dionato-κO3,κO6 (thd) and C∧N = a cyclometalating ligand bearing a pentafluorosulfanyl (−SF5) ...


Estimation of the Thermochemical Radii and Ionic Volumes of Complex Ions

14.06.2017 | Marcus C. Simoes; Kevin J. Hughes; Derek B. Ingham; Lin Ma; Mohamed Pourkashanian, Inorganic Chemistry, 2017

The estimation of the thermochemical radius is very important because most of the properties of the electrolyte solutions are, to some extent, linked to this property. Also, these thermochemical radii can be used to estimate lattice energies, which can be a very important parameter to be ...


Quest for the Ncb-type Metal–Organic Framework Platform: A Bifunctional Ligand Approach Meets Net Topology Needs

14.06.2017 | Di-Ming Chen; Nan-Nan Zhang; Jia-Yue Tian; Chun-Sen Liu; Miao Du, Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b01020


A Highly Selective and Robust Co(II)-Based Homogeneous Catalyst for Reduction of CO2 to CO in CH3CN/H2O Solution Driven by Visible Light

14.06.2017 | Ting Ouyang; Cheng Hou; Jia-Wei Wang; Wen-Ju Liu; Di-Chang Zhong; Zhuo-Feng Ke; Tong-Bu Lu, Inorganic Chemistry, 2017

Visible-light driven reduction of CO2 into chemical fuels has attracted enormous interest in the production of sustainable energy and reversal of the global warming trend. The main challenge in this field is the development of efficient, selective, and economic photocatalysts. Herein, we report a ...


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