Meine Merkliste  

6.363 Aktuelle Fachpublikationen in Inorganic Chemistry


Highly Conductive Li Garnets by a Multielement Doping Strategy

20.03.2015 | Xia Tong; Venkataraman Thangadurai; Eric D. Wachsman, Inorganic Chemistry, 2015

Highly conductive Li7La3Zr2O12 (LLZ) garnet-type solid electrolytes were further optimized to improve Li-ion conduction by La3+-sites substitution with Ba2+ and Zr4+-sites substitution with Ta5+ and Nb5+. Garnet-structured metal oxides of the nominal chemical compositions ...


Electrochemical and Spectroelectrochemical Studies of Diphosphorylated Metalloporphyrins. Generation of a Phlorin Anion Product

19.03.2015 | Yuanyuan Fang; Yulia G. Gorbunova; Ping Chen; Xiaoqin Jiang; Machima Manowong; Anna A. Sinelshchikova; Yulia Yu. Ena ..., Inorganic Chemistry, 2015

Two series of diphosphoryl-substituted porphyrins were synthesized and characterized by electrochemistry and spectroelectrochemistry in nonaqueous media containing 0.1 M tetra-n-butylammonium perchlorate (TBAP). The investigated compounds are 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrins ...


Fabrication of La2Ti2O7 Crystals Using an Alkali-Metal Molybdate Flux Growth Method and Their Nitridability To Form LaTiO2N Crystals under a High-Temperature NH3 Atmosphere

19.03.2015 | Mirabbos Hojamberdiev; Akiko Yamaguchi; Kunio Yubuta; Shuji Oishi; Katsuya Teshima, Inorganic Chemistry, 2015

Flux growth is a promising method that allows one to control over the crystalline phase, crystal shape, crystal size, and crystal surface through the selection of a suitable flux. In this work, lanthanum titanate (La2Ti2O7) crystals with different morphologies were grown using the Na2MoO4, ...


Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs

19.03.2015 | Mohamed B. Taouti; Yan Suffren; Olivier Leynaud; Djamal Benbertal; Alain Brenier; Isabelle Gautier-Luneau, Inorganic Chemistry, 2015

The structural and thermal studies of six anhydrous lanthanum iodate polymorphs are presented. The variation of the [IO3–]:[La3+] molar ratio in the starting solution and the evaporation rate of the solution leads to either the centric La(IO3)3(HIO3) or the acentric La(IO3)3(HIO3)1.33 phases. The ...


Forward and Reverse (Retro) Iron(III) or Gallium(III) Desferrioxamine E and Ring-Expanded Analogues Prepared Using Metal-Templated Synthesis from endo-Hydroxamic Acid Monomers

19.03.2015 | Tulip Lifa; William Tieu; Rosalie K. Hocking; Rachel Codd, Inorganic Chemistry, 2015

A metal-templated synthesis (MTS) approach was used to preorganize the forward endo-hydroxamic acid monomer 4-[(5-aminopentyl)(hydroxy)amino]-4-oxobutanoic acid (for-PBH) about iron(III) in a 1:3 metal/ligand ratio to furnish the iron(III) siderophore for-[Fe(DFOE)] (ferrioxamine E) following ...


CePd2Al2, CePd3Al3, and CePd4Al4—A New Homologous Series Built of CaBe2Ge2- and CsCl-type Units

19.03.2015 | Anna Tursina; Emma Khamitcaeva; Alexander Gribanov; Daniel Gnida; Dariusz Kaczorowski, Inorganic Chemistry, 2015

The aluminides CePd2Al2, CePd3Al3, and CePd4Al4 were synthesized and their properties studied by X-ray diffraction, magnetic, heat capacity, and electrical transport measurements. The crystal structures of CePd2Al2 and CePd4Al4 were determined and refined from the single-crystal X-ray diffraction ...


Heterolytic Activation of C–H Bonds on CrIII–O Surface Sites Is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane

19.03.2015 | Matthew P. Conley; Murielle F. Delley; Francisco Núñez-Zarur; Aleix Comas-Vives; Christophe Copéret, Inorganic Chemistry, 2015

We describe the reactivity of well-defined chromium silicates toward ethylene and propane. The initial motivation for this study was to obtain a molecular understanding of the Phillips polymerization catalyst. The Phillips catalyst contains reduced chromium sites on silica and catalyzes the ...


Syntheses of Tricyanofluoroborates M[BF(CN)3] (M = Na, K): (CH3)3SiCl Catalysis, Countercation Effect, and Reaction Intermediates

18.03.2015 | Jan A. P. Sprenger; Johannes Landmann; Michael Drisch; Nikolai Ignat’ev; Maik Finze, Inorganic Chemistry, 2015

Potassium tricyanofluoroborate, K[BF(CN)3], which is the starting material for tricyanofluoroborate room-temperature ionic liquids [N. Ignat’ev et al. J. Fluorine Chem., submitted] was obtained on a molar scale (140 g) from Na[BF4] and (CH3)3SiCN with a purity of up to 99.9%. The initial product ...


A Bifunctional, Site-Isolated Metal–Organic Framework-Based Tandem Catalyst

18.03.2015 | Phuong V. Dau; Seth M. Cohen, Inorganic Chemistry, 2015

Herein, we present the synthesis of a metal–organic framework-based tandem catalyst that contains two distinct catalytic domains. Zn(II)-based IRMOF-9-Irdcppy-NH2 (IRMOF = isoreticular metal–organic framework) has both organocatalytic amine and organometallic Ir(I) groups that were incorporated ...


A Study on the Effect of Dianionic Tridentate Ligands on the Radiative and Nonradiative Processes for Gold(III) Alkynyl Systems by a Computational Approach

18.03.2015 | Elizabeth Suk-Hang Lam; Wai Han Lam; Vivian Wing-Wah Yam, Inorganic Chemistry, 2015

Gold(III) alkynyl complexes with dianionic tridentate pincer ligands have received growing attention recently because of their rich luminescence behavior and their potential applications in areas such as optoelectronics and sensors. In this study, density functional theory (DFT) and ...


Seite 1 von 637
Suche per e-Mail abonnieren

Sie erhalten passend zu Ihrer Suche die neusten Suchergebnisse per E-Mail. Dieser Service ist für Sie kostenlos und kann jederzeit abbestellt werden.

Ihr Bowser ist nicht aktuell. Microsoft Internet Explorer 6.0 unterstützt einige Funktionen auf Chemie.DE nicht.