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5.493 Aktuelle Fachpublikationen in Inorganic Chemistry

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Valence State Driven Site Preference in the Quaternary Compound Ca5MgAgGe5: An Electron-Deficient Phase with Optimized Bonding

18.04.2014 | Siméon Ponou; Sven Lidin; Yuemei Zhang; Gordon J. Miller, Inorganic Chemistry, 2014

The quaternary phase Ca5Mg0.95Ag1.05(1)Ge5 (3) was synthesized by high-temperature solid-state techniques, and its crystal structure was determined by single-crystal diffraction methods in the orthorhombic space group Pnma – Wyckoff sequence c12 with a = 23.1481(4) Å, b = 4.4736(1) Å, c = ...

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Synthesis, Structure, and Magnetic Properties of (Tb1–xMny)MnO3−δ

18.04.2014 | Hao Zhang; Roxana Flacau; Junliang Sun; Guobao Li; Fuhui Liao; Jianhua Lin, Inorganic Chemistry, 2014

Two compounds (Tb1–xMny)MnO3−δ (W1, x = 0.089, y = 0.063; W2, x = 0.122, y = 0.102) have been synthesized by solid-state method and characterized using neutron diffraction and magnetic measurements. They crystallize in space group Pnma at room temperature and Pna21 at low temperature. W1 shows a ...

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Modeling Biological Copper Clusters: Synthesis of a Tricopper Complex, and Its Chloride- and Sulfide-Bridged Congeners

18.04.2014 | Gianna N. Di Francesco; Aleth Gaillard; Ion Ghiviriga; Khalil A. Abboud; Leslie J. Murray, Inorganic Chemistry, 2014

The synthesis and characterization of a family of tricopper clusters housed within a tris(β-diketimine) cyclophane ligand (H3L) that bear structural similarities to biological copper clusters are reported. In all complexes, each Cu atom is held within the N2-chelate of a single β-diketiminate ...

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Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors

18.04.2014 | Irene Bassanetti; Christina P. Twist; Myung-Gil Kim; Afif M. Seyam; Hassan S. Bazzi; Q. Jane Wang; Yip-Wah Chung; Lu ..., Inorganic Chemistry, 2014

A series of light- and air-stable silver(I) pyrazolylmethylpyridine complexes [Ag(LR)]n(BF4)n (L = pyrazolylmethylpyridine; R = H, 1; R = Me, 2; R = i-Pr, 3) and [Ag(LR)(NO3)]2 (L = pyrazolylmethylpyridine; R = H, 4; R = Me, 5; R = i-Pr, 6) has been synthesized and structurally and ...

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Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium Hydroxo—Aquo Clusters

18.04.2014 | Maisha K. Kamunde-Devonish; Milton N. Jackson, Jr.; Zachary L. Mensinger; Lev N. Zakharov; Darren W. Johnson, Inorganic Chemistry, 2014

Inorganic Chemistry DOI: 10.1021/ic403121r

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Introducing a New Azoaromatic Pincer Ligand. Isolation and Characterization of Redox Events in Its Ferrous Complexes

17.04.2014 | Pradip Ghosh; Subhas Samanta; Suman K. Roy; Serhiy Demeshko; Franc Meyer; Sreebrata Goswami, Inorganic Chemistry, 2014

The isolation and complete characterization of a new bis-azoaromatic ligand, 2,6-bis(phenylazo)pyridine (L), are described, and its coordination to iron(II) is reported. A pseudo-trigonal-bipyramidal mixed-ligand complex of iron(II), FeLCl2 (1), and a homoleptic octahedral iron complex, ...

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Chiral Single-Chain Magnet: Helically Stacked [MnIII2CuII] Triangles

17.04.2014 | Takuya Shiga; Kazuya Maruyama; Graham N. Newton; Ross Inglis; Euan K. Brechin; Hiroki Oshio, Inorganic Chemistry, 2014

Inorganic Chemistry DOI: 10.1021/ic5002418

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CO and CO2 Fixation by Se–Ru–CO Hydride Clusters

17.04.2014 | Minghuey Shieh; Yen-Yi Chu; Li-Fing Jang; Chia-Hua Ho, Inorganic Chemistry, 2014

The selective insertion of CO and CO2 into the C–O and O–H bonds of alcohols by the Se–Ru–CO hydride clusters [(μ-H)Ru4(CO)10Se2]− (1) and [(μ3-H)Ru5(CO)14Se]− (2) was demonstrated by a cooperative effect of the protonic hydride, the electron-rich Ru atom, and the electronegative Se atom as well ...

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Unexpected NO Transfer Reaction between trans-[RuII(NO+)(NH3)4(L)]3+ and Fe(III) Species: Observation of a Heterobimetallic NO-Bridged Intermediate

16.04.2014 | Gustavo Metzker; Pietro P. Lopes; Augusto C. H. da Silva; Sebastiao C. da Silva; Douglas W. Franco, Inorganic Chemistry, 2014

The reaction between trans-[RuII(NO+)(NH3)4(L)]3+, L = ImN, IsN, Nic, P(OMe)3, P(OEt)3, and P(OH)(OEt)2, and the Fe(III) species [FeIII(TPPS)], metmyoglobin, and hemoglobin was monitored by UV–vis, EPR, and electrochemical techniques (DPV, CV). No reaction was observed when L = ImN, IsN, Nic, and ...

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Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

16.04.2014 | M. Angeles Alvarez; M. Esther García; Daniel García-Vivó; Sonia Melón; Miguel A. Ruiz; Adrián Toyos, Inorganic Chemistry, 2014

The dicarbonyl complex trans-[W2Cp2(μ-PPh2)2(CO)2] (Cp = η5-C5H5) reacted rapidly with NO (5% in N2) at 273 K to give selectively cis-[W2Cp2(μ-PPh2)2(NO)2]. In contrast, the analogous reactions of monocarbonyl [W2Cp2(μ-PPh2)2(μ-CO)] yielded either trans-[W2Cp2(μ-PPh2)2(NO)2] or the nitrito ...

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