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8.503 Aktuelle Fachpublikationen in Inorganic Chemistry


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Isomeric Sc2O@C78 Related by a Single-Step Stone–Wales Transformation: Key Links in an Unprecedented Fullerene Formation Pathway

09.10.2016 | Yajuan Hao; Qiangqiang Tang; Xiaohong Li; Meirong Zhang; Yingbo Wan; Lai Feng; Ning Chen; Zdeněk Slanina; Ludwik Ada ..., Inorganic Chemistry, 2016

It has been proposed that the fullerene formation mechanism involves either a top-down or bottom-up pathway. Despite different starting points, both mechanisms approve that particular fullerenes or metallofullerenes are formed through a consecutive stepwise process involving Stone–Wales ...


Designing Multifunctional 5-Cyanoisophthalate-Based Coordination Polymers as Single-Molecule Magnets, Adsorbents, and Luminescent Materials

07.10.2016 | Jose M. Seco; Itziar Oyarzabal; Sonia Pérez-Yáñez; Javier Cepeda; Antonio Rodríguez-Diéguez, Inorganic Chemistry, 2016

Detailed structural, magnetic, and photoluminescence characterization of a family of new compounds based on 5-cyanoisophthalate (CNip) ligand and several transition metal or lanthanide ions, namely, [Cu3(μ3-CNip)2(μ-H2O)2(μ3-OH)2]n (1), {[Co3(μ4-CNip)3(DMF)4]·∼2DMF}n (2), [Cd(μ4-CNip) (DMF)]n ...


Synthesis and Isomeric Analysis of RuII Complexes Bearing Pentadentate Scaffolds

07.10.2016 | Marcos Gil-Sepulcre; Jordan C. Axelson; Joan Aguiló; Lluís Solà-Hernández; Laia Francàs; Albert Poater; Lluís Blanca ..., Inorganic Chemistry, 2016

A RuII-pentadentate polypyridyl complex [RuII(κ-N5-bpy2PYMe)Cl]+ (1+, bpy2PYMe = 1-(2-pyridyl)-1,1-bis(6–2,2′-bipyridyl)ethane) and its aqua derivative [RuII(κ-N5-bpy2PYMe)(H2O)]2+ (22+) were synthesized and characterized by experimental and computational methods. In MeOH, 1+ exists as two ...


Probing the Effect of Axial Ligands on Easy-Plane Anisotropy of Pentagonal-Bipyramidal Cobalt(II) Single-Ion Magnets

07.10.2016 | Dong Shao; Shao-Liang Zhang; Le Shi; Yi-Quan Zhang; Xin-Yi Wang, Inorganic Chemistry, 2016

We herein reported the synthetic, structural, computational, and magnetic studies of four air-stable heptacoordinated mononuclear cobalt(II) complexes, namely, [CoII(tdmmb)(H2O)2][BF4]2 (1), [CoII(tdmmb)(CN)2]·2H2O (2), [CoII(tdmmb)(NCS)2] (3), and [CoII(tdmmb)(SPh)2] (4) (tdmmb = ...


Ethylenediamine-Assisted Hydrothermal Synthesis of NaCaSiO3OH: Controlled Morphology, Mechanism, and Luminescence Properties by Doping Eu3+/Tb3+

07.10.2016 | Mingyue Chen; Zhiguo Xia; Quanlin Liu, Inorganic Chemistry, 2016

This paper demonstrates a facile hydrothermal method using ethylenediamine (EDA) as a “shape modifier” for the controlled synthesis of rod bunch, decanedron, spindle, flakiness, and flowerlike NaCaSiO3OH microarchitectures. The set of experimental conditions is important to obtain adjustable ...


Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

06.10.2016 | Isabel G. Albuerne; M. Angeles Alvarez; Inmaculada Amor; M. Esther García; Daniel García-Vivó; Miguel A. Ruiz, Inorganic Chemistry, 2016

The title phosphinidene complex reacted at room temperature with CS2 and SCNPh to give the phosphanyl derivatives [Mo2Cp{μ-κ2P,S:κ1S′,η5-P(CS2)C5H4}(CO)2(η6-HMes*)] and [Mo2Cp{μ-κ2P,S:κ1P,η5-P(C(NPh)S)C5H4}(CO)2(η6-HMes*)], respectively (Mes* = 2,4,6-C6H2tBu3), which result from a [2 + 2] ...


Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material

06.10.2016 | Natasha F. Sciortino; Florence Ragon; Katrina A. Zenere; Peter D. Southon; Gregory J. Halder; Karena W. Chapman; Luc ..., Inorganic Chemistry, 2016

A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of strategically producing multistep spin transitions in two-dimensional Hofmann-type materials of the type [FeIIPd(CN)4(R-1,2,4-trz)2]·nH2O ...


Ultrafast Singlet Energy Transfer in Porphyrin Dyads

06.10.2016 | Hervé Dekkiche; Antoine Buisson; Adam Langlois; Paul-Ludovic Karsenti; Laurent Ruhlmann; Pierre D. Harvey; Romain Ru ..., Inorganic Chemistry, 2016

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.6b01594


Azole Functionalized Polyoxo-Titanium Clusters with Sunlight-Driven Dye Degradation Applications: Synthesis, Structure, and Photocatalytic Studies

06.10.2016 | Nagaraju Narayanam; Kalpana Chintakrinda; Wei-Hui Fang; Yao Kang; Lei Zhang; Jian Zhang, Inorganic Chemistry, 2016

Six polyoxo-titanium clusters (PTCs) with varying nuclearities containing Ti–N bonds and heteronuclearity, namely, [Ti6(μ3-O)2(μ2-O)2(O3P-Phen)2(OiPr)10(1-hbta)2] (PTC-37), Ti8(μ3-O)2(μ2-O)2(O3P-Phen)2(OiPr)16(adn)2(NO3)2] (PTC-38), [Ti4(μ3-O)(μ2-O)(μ2-OiPr)2(OiPr)4(O3P-Phen)3(1,10-phn)](HOiPr) ...


Exploring the Chemical Reactivity between Carbon Dioxide and Three Transition Metals (Au, Pt, and Re) at High-Pressure, High-Temperature Conditions

06.10.2016 | David Santamaría-Pérez; Chris McGuire; Adam Makhluf; Abby Kavner; Raquel Chuliá-Jordán; Julio Pellicer-Porres; Domin ..., Inorganic Chemistry, 2016

The role of carbon dioxide, CO2, as oxidizing agent at high pressures and temperatures is evaluated by studying its chemical reactivity with three transition metals: Au, Pt, and Re. We report systematic X-ray diffraction measurements up to 48 GPa and 2400 K using synchrotron radiation and ...


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