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6.448 Aktuelle Fachpublikationen in Inorganic Chemistry

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Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex

22.04.2015 | Anna Lewandowska-Andralojc; Teera Baine; Xuan Zhao; James T. Muckerman; Etsuko Fujita; Dmitry E. Polyansky, Inorganic Chemistry, 2015

The ability of cobalt-based transition metal complexes to catalyze electrochemical proton reduction to produce molecular hydrogen has resulted in a large number of mechanistic studies involving various cobalt complexes. While the basic mechanism of proton reduction promoted by cobalt species is ...

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Cation-Exchange Porosity Tuning in a Dynamic 4d–4f–3d Framework for NiII Ion-Selective Luminescent Probe

17.04.2015 | Ying Wang; Xiu-Guang Wang; Bin Yuan; Cheng-Yuan Shao; Yuan-Yuan Chen; Bing-Bing Zhou; Ming-Shu Li; Xiao-Mai An; Peng ..., Inorganic Chemistry, 2015

A heterometallic complex {[Yb2(L)6Cd2][Cd(H2O)6]·6H2O}n (Yb–Cd) (H2L = oxidiacetic acid) was synthesized under hydrothermal conditions. In Yb–Cd, each L chelates to one Yb3+ center and bonds to two Cd2+ ions in an anti-anti configuration. Yb and Cd atoms are arrayed alternatively and connected by ...

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Structure–Function Relationships for Electrocatalytic Water Oxidation by Molecular [Mn12O12] Clusters

17.04.2015 | Yong Yan; John S. Lee; Daniel A. Ruddy, Inorganic Chemistry, 2015

A series of Mn12O12(OAc)16–xLx(H2O)4 molecular clusters (L = acetate, benzoate, benzenesulfonate, diphenylphosphonate, dichloroacetate) were electrocatalytically investigated as water oxidation electrocatalysts on a fluorine-doped tin oxide glass electrode. Four of the [Mn12O12] compounds ...

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Binding Studies of G-Quadruplex DNA and Porphyrins: Cu(T4) vs Sterically Friendly Cu(tD4)

17.04.2015 | Abby J. Gaier; David R. McMillin, Inorganic Chemistry, 2015

This investigation explores binding interactions involving G-quadruplex DNA and two copper(II)-containing porphyrins (5,10,15,20-tetra(N-methylpyridinium-4-yl)porphyrinato)copper(II) and the sterically friendlier analogue (trans-5,15-di(N-methylpyridinium-4-yl)porphyrinato)copper(II), or Cu(T4) ...

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Intramolecular Ferromagnetic Radical–CuII Coupling in a CuII Complex Ligated with Pyridyl-Substituted Triarylmethyl Radicals

17.04.2015 | Tetsuro Kusamoto; Yohei Hattori; Akira Tanushi; Hiroshi Nishihara, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b00499

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Formation and Transmetalation Mechanisms of Homo- and Heterometallic (Fe/Zn) Trinuclear Triple-Stranded Side-by-Side Helicates

16.04.2015 | Bidyut Akhuli; Luca Cera; Barun Jana; Subrata Saha; Christoph A. Schalley; Pradyut Ghosh, Inorganic Chemistry, 2015

A novel linear hybrid tris-bidentate neutral ligand having 2,2′-bipyridine and two terminal triazolylpyridine coordination sites (L) was efficiently synthesized and explored in the synthesis of trinuclear triple-stranded homometallic side-by-side helicates L3Fe3(OTf)6 (1) and L3Zn3(OTf)6 (2), in ...

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Novel Microporous Metal–Organic Framework Exhibiting High Acetylene and Methane Storage Capacities

15.04.2015 | Xing Duan; Chuande Wu; Shengchang Xiang; Wei Zhou; Taner Yildirim; Yuanjing Cui; Yu Yang; Banglin Chen; Guodong Qian, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b00194

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Corrole-BODIPY Dyads: Synthesis, Structure, and Electrochemical and Photophysical Properties

15.04.2015 | Biju Basumatary; Adiki Raja Sekhar; R. V. Ramana Reddy; Jeyaraman Sankar, Inorganic Chemistry, 2015

A free-base and its Cu(III) derivative of bichromophoric meso-β linked corrole-BODIPY dyad were synthesized and structurally characterized by single crystal X-ray diffraction (XRD). Both corrole and BODIPY fragments maintained respective ground state electronic isolation despite their connection ...

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Electronic and Steric Influences of Pendant Amine Groups on the Protonation of Molybdenum Bis(dinitrogen) Complexes

14.04.2015 | Liezel A. Labios; Zachariah M. Heiden; Michael T. Mock, Inorganic Chemistry, 2015

The synthesis of a series of PEtPNRR′ (PEtPNRR′ = Et2PCH2CH2P(CH2NRR′)2, R = H, R′ = Ph or 2,4-difluorophenyl; R = R′ = Ph or iPr) diphosphine ligands containing mono- and disubstituted pendant amine groups and the preparation of their corresponding molybdenum bis(dinitrogen) complexes ...

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C–F Bond Activation by Transient Phosphenium Dications

14.04.2015 | Nemanja Đorđević; Madelyn Qin Yi Tay; Senthilkumar Muthaiah; Rakesh Ganguly; Dušan Dimić; Dragoslav Vidović, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/ic5031125

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