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5.808 Aktuelle Fachpublikationen in Inorganic Chemistry

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Photoreduction of Pt(IV) Chloro Complexes: Substrate Chlorination by a Triplet Excited State

27.06.2014 | Tharushi A. Perera; Mehdi Masjedi; Paul R. Sharp, Inorganic Chemistry, 2014

The Pt(IV) complexes trans-Pt(PEt3)2(Cl)3(R) 2 (R = Cl, Ph, 9-phenanthryl, 2-trifluoromethylphenyl, 4-trifluoromethylphenyl, 3-perylenyl) were prepared by chlorination of the Pt(II) complexes trans-Pt(PEt3)2(R)(Cl) 1 with Cl2(g) or PhICl2. Mixed bromo–chloro complexes ...

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Stereoelectronic Effects in C–H Bond Oxidation Reactions of Ni(I) N-Heterocyclic Carbene Complexes

27.06.2014 | Rebecca C. Poulten; Isidoro López; Antoni Llobet; Mary F. Mahon; Michael K. Whittlesey, Inorganic Chemistry, 2014

Activation of O2 by the three-coordinate Ni(I) ring-expanded N-heterocyclic carbene complexes Ni(RE-NHC)(PPh3)Br (RE-NHC = 6-Mes, 1; 7-Mes, 2) produced the structurally characterized dimeric Ni(II) complexes Ni(6-Mes)(Br)(μ-OH)(μ-O-6-Mes′)NiBr (3) and Ni(7-Mes)(Br)(μ-OH)(μ-O-7-Mes′)NiBr (4) ...

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Synthesis and Characterization of Electron Donor–Acceptor Platinum(II) Complexes Composed of N,N-Diphenylpyridineamine and Triphenylamine Ligands

27.06.2014 | Zhi Dai; Alejandro J. Metta-Magaña; Jose E. Nuñez, Inorganic Chemistry, 2014

The synthesis and electronic properties of a series of platinum(II) complexes composed of electron-donor and electron-acceptor components as potential photovoltaic materials is reported. The complexes are composed of triphenylamines (TPA) and pyridine-derivatized TPAs as the electron-donating ...

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Construction of Non-Interpenetrated Charged Metal–Organic Frameworks with Doubly Pillared Layers: Pore Modification and Selective Gas Adsorption

27.06.2014 | Susan Sen; Subhadip Neogi; Arshad Aijaz; Qiang Xu; Parimal K. Bharadwaj, Inorganic Chemistry, 2014

The rigid and angular tetracarboxylic acid 1,3-bis(3,5-dicarboxyphenyl)imidazolium (H4L+), incorporating an imidazolium group, has been used with different pyridine-based linkers to construct a series of non-interpenetrated cationic frameworks, {[Zn2(L)(bpy)2]·(NO3)·(DMF)6·(H2O)9}n (1), ...

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Toward Coordination Polymers Based on Fine-Tunable Group 13 Organometallic Phthalates

27.06.2014 | Iwona Justyniak; Wojciech Bury; Daniel Prochowicz; Katarzyna Wójcik; Janusz Zachara; Janusz Lewiński, Inorganic Chemistry, 2014

A family of group 13 organometallic macrocyclic phthalates [(MMe2)2(μ-O2C)2-1,2-C6H4]2 (where M = Al (1), Ga (2), In (3)) is prepared, and the reactivity of these homologous carboxylates toward various monodentate Lewis bases is investigated. The studies provide the first structurally ...

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A Double Substitution of Mg2+–Si4+/Ge4+ for Al(1)3+–Al(2)3+ in Ce3+-Doped Garnet Phosphor for White LEDs

27.06.2014 | Mengmeng Shang; Jian Fan; Hongzhou Lian; Yang Zhang; Dongling Geng; Jun Lin, Inorganic Chemistry, 2014

The influence of Mg2+–Si4+/Ge4+ incorporation into Ce3+-doped Y3Al5O12 garnet phosphors on the crystal structure and luminescence properties is described in this work. X-ray diffraction with Rietveld refinements, photoluminescence spectra, absolute quantum yield, thermal quenching behavior, and ...

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Characterization of the Bridged Hyponitrite Complex {[Fe(OEP)]2(μ-N2O2)}: Reactivity of Hyponitrite Complexes and Biological Relevance

27.06.2014 | Timothy C. Berto; Nan Xu; Se Ryeon Lee; Anne J. McNeil; E. Ercan Alp; Jiyong Zhao; George B. Richter-Addo; Nicolai L ..., Inorganic Chemistry, 2014

The detoxification of nitric oxide (NO) by bacterial NO reductase (NorBC) represents a paradigm of how NO can be detoxified anaerobically in cells. In order to elucidate the mechanism of this enzyme, model complexes provide a convenient means to assess potential reaction intermediates. In ...

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Preparation and Dehydrogenation Properties of Lithium Hydrazidobis(borane) (LiNH(BH3)NH2BH3)

27.06.2014 | He Fu; Junzhi Yang; Xiaojuan Wang; Gongbiao Xin; Jie Zheng; Xingguo Li, Inorganic Chemistry, 2014

LiNH(BH3)NH2BH3, the first example of metal-substituted hydrazine bisborane (HBB), is synthesized via the reaction between HBB and n-butyllithium in ether solution. 11B NMR and Fourier transform infrared spectroscopy indicate a new structure, in which one of the N–H bonds is replaced by a N–Li ...

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Synthesis, Crystal Structure, and TEM Analysis of Sr19Li44 and Sr3Li2: A Reinvestigation of the Sr–Li Phase Diagram

27.06.2014 | Volodymyr Smetana; Lorenz Kienle; Viola Duppel; Arndt Simon, Inorganic Chemistry, 2014

Two intermetallic phases in the Sr–Li system have been synthesized and structurally characterized. According to single-crystal X-ray diffraction data, Sr19Li44 and Sr3Li2 crystallize with tetragonal unit cells (Sr19Li44, I-42d, a = 15.9122(7) Å, c = 31.831(2) Å, Z = 4, V = 8059(2) Å3; Sr3Li2, ...

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Network Flexibility: Control of Gate Opening in an Isostructural Series of Ag-MOFs by Linker Substitution

26.06.2014 | Marcel Handke; Hanna Weber; Marcus Lange; Jens Möllmer; Jörg Lincke; Roger Gläser; Reiner Staudt; Harald Krautscheid, Inorganic Chemistry, 2014

An isostructural series of 15 structurally flexible microporous silver metal–organic frameworks (MOFs) is presented. The compounds with a dinuclear silver core as secondary building unit (Ag2N4) can be obtained under solvothermal conditions from substituted triazolyl benzoate linkers and AgNO3 or ...

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