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7.966 Aktuelle Fachpublikationen in Inorganic Chemistry


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Carbonate-Bridged Lanthanoid Triangles: Single-Molecule Magnet Behavior, Inelastic Neutron Scattering, and Ab Initio Studies

20.05.2016 | Marcus J. Giansiracusa; Michele Vonci; Willem Van den Heuvel; Robert W. Gable; Boujemaa Moubaraki; Keith S. Murray; ..., Inorganic Chemistry, 2016

Optimization of literature synthetic procedures has afforded, in moderate yield, homogeneous and crystalline samples of the five analogues Na11[{RE(OH2)}3CO3(PW9O34)2] (1-RE; RE = Y, Tb, Dy, Ho, and Er). Phase-transfer methods have allowed isolation of the mixed salts ...


Unusual Synthetic Pathway for an {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC) and Insight into DNIC Electronic Structure via Nuclear Resonance Vibrational Spectroscopy

20.05.2016 | Amy L. Speelman; Bo Zhang; Alexey Silakov; Kelsey M. Skodje; E. Ercan Alp; Jiyong Zhao; Michael Y. Hu; Eunsuk Kim; C ..., Inorganic Chemistry, 2016

Dinitrosyl iron complexes (DNICs) are among the most abundant NO-derived cellular species. Monomeric DNICs can exist in the {Fe(NO)2}9 or {Fe(NO)2}10 oxidation state (in the Enemark–Feltham notation). However, experimental studies of analogous DNICs in both oxidation states are rare, which ...


Synthesis and Photochromic Studies of Dithienylethene-Containing Cyclometalated Alkynylplatinum(II) 1,3-Bis(N-alkylbenzimidazol-2′-yl)benzene Complexes

20.05.2016 | Michael Ho-Yeung Chan; Hok-Lai Wong; Vivian Wing-Wah Yam, Inorganic Chemistry, 2016

Several photochromic cyclometalated alkynylplatinum(II) complexes with tridentate 1,3-bis(N-alkylbenzimidazol-2′-yl)benzene (bzimb) ligands have been synthesized by the reaction of the corresponding chloroplatinum(II) bzimb precursor complexes with the photochromic ligand TMS-C≡C-Th-DTE in the ...


Nanoscale Synthesis of Two Porphyrin-Based MOFs with Gallium and Indium

20.05.2016 | Timo Rhauderwiek; Steve Waitschat; Stefan Wuttke; Helge Reinsch; Thomas Bein; Norbert Stock, Inorganic Chemistry, 2016

Two porphyrin-based metal–organic frameworks (MOFs) containing gallium or indium, [Ga2(OH)2(H2TCPP)]·3DMF·3H2O (Ga-PMOF) and [In2(OH)2(H2TCPP)]·3DMF·4H2O (In-PMOF) (H6TCPP = 4-tetracarboxyphenylporphyrin), were discovered using high-throughput methods. The structure was refined by the ...


Taming Lanthanide-Centered Upconversion at the Molecular Level

20.05.2016 | Yan Suffren; Bahman Golesorkhi; Davood Zare; Laure Guénée; Homayoun Nozary; Svetlana V. Eliseeva; Stéphane Petoud; A ..., Inorganic Chemistry, 2016

Considered at the beginning of the 21th century as being incompatible with the presence of closely bound high-energy oscillators, lanthanide-centered superexcitation, which is the raising of an already excited electron to an even higher level by excited-state energy absorption, is therefore a ...


Probing the Reactivity of the Ce═O Multiple Bond in a Cerium(IV) Oxo Complex

19.05.2016 | Yat-Ming So; Yang Li; Ka-Chun Au-Yeung; Guo-Cang Wang; Kang-Long Wong; Herman H. Y. Sung; Polly L. Arnold; Ian D. Wi ..., Inorganic Chemistry, 2016

The reactivity of the cerium(IV) oxo complex [(LOEt)2CeIV(═O)(H2O)]·MeC(O)NH2 (1; LOEt– = [CoCp{P(O)(OEt)2}3]−, where Cp = η5-C5H5) toward electrophiles and Brønsted acids has been investigated. The treatment of 1 with acetic anhydride afforded the diacetate complex [CeIV(LOEt)2(O2CMe)2] (2). The ...


Metal–Organic Framework Based on Isonicotinate N-Oxide for Fast and Highly Efficient Aqueous Phase Cr(VI) Adsorption

19.05.2016 | Leila Aboutorabi; Ali Morsali; Elham Tahmasebi; Orhan Büyükgüngor, Inorganic Chemistry, 2016

Synthesis of new porous materials has been developed for efficient capture of pollutants in environmental sciences. Here, the application of a new metal–organic framework (TMU-30) has been reported based on isonicotinate N-oxide as an adsorptive site for fast and highly efficient aqueous phase ...


Novel Convenient Synthesis of 10B-Enriched Sodium Borohydride

19.05.2016 | Alexander V. Safronov; Satish S. Jalisatgi; M. Frederick Hawthorne, Inorganic Chemistry, 2016

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.6b01002


Lanthanide-Directed Fabrication of Four Tetranuclear Quadruple Stranded Helicates Showing Magnetic Refrigeration and Slow Magnetic Relaxation

19.05.2016 | Amit Kumar Mondal; Himanshu Sekhar Jena; Amita Malviya; Sanjit Konar, Inorganic Chemistry, 2016

A rare class of four tetranuclear lanthanide based quadruple stranded helicates namely, [Ln4L4(OH)2](OAc)2·xH2O (Ln = GdIII(1), DyIII(2) and x = 4, 5 respectively), [Er4L4(OH)2](NO3)2·9H2O (3), and [Dy4L4(NO3)](NO3)2·2CH3OH·H2O (4) were synthesized by employing succinohydrazone derived ...


Mono- and Dinuclear Manganese Carbonyls Supported by 1,8-Disubstituted (L = Py, SMe, SH) Anthracene Ligand Scaffolds

19.05.2016 | Taylor A. Manes; Michael J. Rose, Inorganic Chemistry, 2016

Presented herein is a synthetic scheme to generate symmetric and asymmetric ligands based on a 1,8-disubstituted anthracene scaffold. The metal-binding scaffolds were prepared by aryl chloride activation of 1,8-dichloroanthracene using Suzuki-type couplings facilitated by [Pd(dba)2] as a Pd ...


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