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7.293 Aktuelle Fachpublikationen in Inorganic Chemistry


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Chiral Platinum(II) Complexes Featuring Phosphine and Chloroquine Ligands as Cytotoxic and Monofunctional DNA-Binding Agents

25.11.2015 | Wilmer Villarreal; Legna Colina-Vegas; Clayton Rodrigues de Oliveira; Juan C. Tenorio; Javier Ellena; Fábio C. Gozzo ..., Inorganic Chemistry, 2015

Chiral molecules in nature are involved in many biological events; their selectivity and specificity make them of great interest for understanding the behavior of bioactive molecules, by providing information about the chiral discrimination. Inspired by these conformational properties, we present ...


Synthesis and Characterization of Palladium(II) Complexes of meso-Substituted [14]Tribenzotriphyrin(2.1.1)

25.11.2015 | Zhaoli Xue; Yemei Wang; John Mack; Yuanyuan Fang; Zhongping Ou; Weihua Zhu; Karl M. Kadish, Inorganic Chemistry, 2015

Metalation of 6,13,20,21-tetrakis-aryl-22H-[14]tribenzotriphyrin(2.1.1) (TriPs) with PdCl2 provides PdII–TriP complexes in 45–56% yields. The complexes were characterized by mass spectrometry, and UV–visible absorption, magnetic circular dichroism, and 1H NMR spectroscopy. A single crystal X-ray ...


Synthesis, Structure, and Bonding for Bis(permethylpentalene)diiron

25.11.2015 | Samantha C. Binding; Jennifer C. Green; William K. Myers; Dermot O’Hare, Inorganic Chemistry, 2015

The synthesis of the first homoleptic double metallocene complex of iron, Fe2Pn*2 (Pn* = permethylpentalene, C8Me6) is described. The structural and electronic properties of Fe2Pn*2 have been characterized by NMR and EPR spectroscopy, single crystal X-ray diffraction, magnetic measurements, ...


Synthesis and Photophysical Study of a [NiFe] Hydrogenase Biomimetic Compound Covalently Linked to a Re-diimine Photosensitizer

25.11.2015 | Peter A. Summers; James A. Calladine; Fabio Ghiotto; Joe Dawson; Xue-Z. Sun; Michelle L. Hamilton; Michael Towrie; E ..., Inorganic Chemistry, 2015

The synthesis, photophysics, and photochemistry of a linked dyad ([Re]-[NiFe2]) containing an analogue ([NiFe2]) of the active site of [NiFe] hydrogenase, covalently bound to a Re-diimine photosensitizer ([Re]), are described. Following excitation, the mechanisms of electron transfer involving ...


Effect of Isovalent Substitution on the Structure and Properties of the Zintl Phase Solid Solution Eu7Cd4Sb8–xAsx (2 ≤ x ≤ 5)

25.11.2015 | Joya Cooley; Nasrin Kazem; Julia V. Zaikina; James C. Fettinger; Susan M. Kauzlarich, Inorganic Chemistry, 2015

A novel Zintl phase structure type, Eu7Cd4Sb8–xAsx (x = 2, 3, 4, and 5), with the general formula Eu7Cd4Pn8 (Pn = mixed occupancy Sb and As), was synthesized by molten tin flux reaction. Its structure was determined using single-crystal X-ray diffraction methods. This structure type is only ...


Early-Lanthanide(III) Acetonitrile–Solvento Adducts with Iodide and Noncoordinating Anions

25.11.2015 | Jessie L. Brown; Benjamin L. Davis; Brian L. Scott; Andrew J. Gaunt, Inorganic Chemistry, 2015

Dissolution of LnI3 (Ln = La, Ce) in acetonitrile (MeCN) results in the highly soluble solvates LnI3(MeCN)5 [Ln = La (1), Ce (2)] in good yield. The ionic complex [La(MeCN)9][LaI6] (4), containing a rare homoleptic La3+ cation and anion, was also isolated as a minor product. Extending this ...


Whole-Visible-Light Absorption of a Mixed-Valence Silver Vanadate Semiconductor Stemming from an Assistant Effect of d–d Transition

25.11.2015 | Hongjun Dong; Gang Chen; Jingxue Sun; Chunmei Li; Yidong Hu; Zhonghui Han, Inorganic Chemistry, 2015

Wide-light absorption is important to semiconductors exploited in many applications such as photocatalysts, photovoltaic devices, and light-emitting diodes, which can effectively improve solar energy utilization. Especially for photocatalysts, the development and design of new semiconductors that ...


Syntheses of Diphenylaminodiazidophosphane and Diphenylaminofluoroazidophosphane

25.11.2015 | William W. Wilson; Andrew J. Clough; Ralf Haiges; Martin Rahm; Karl O. Christe, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b02097


Jahn–Teller Effect in the B12F12 Radical Anion and Energetic Preference of an Octahedral B6(BF2)6 Cluster Structure over an Icosahedral Structure for the Elusive Neutral B12F12

25.11.2015 | Moritz Malischewski; Eric V. Bukovsky; Steven H. Strauss; Konrad Seppelt, Inorganic Chemistry, 2015

The B12F12– radical anion was generated by oxidation of [CoCp2+]2B12F122– with AsF5 in SO2. In the crystal structure of [CoCp2+]B12F12–, the anion displays a lowered symmetry (D2h) instead of an Ih-symmetric dianion as a result of Jahn–Teller distortion. Moreover, shortening of the B–F bonds and ...


Dinuclear Zinc Salen Catalysts for the Ring Opening Copolymerization of Epoxides and Carbon Dioxide or Anhydrides

25.11.2015 | Arnaud Thevenon; Jennifer A. Garden; Andrew J. P. White; Charlotte K. Williams, Inorganic Chemistry, 2015

A series of four dizinc complexes coordinated by salen or salan ligands, derived from ortho-vanillin and bearing (±)-trans-1,2-diaminocyclohexane (L1) or 2,2-dimethyl-1,3-propanediamine (L2) backbones, is reported. The complexes are characterized using a combination of X-ray crystallography, ...


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