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6.753 Aktuelle Fachpublikationen in Inorganic Chemistry

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Rhenium Complex with Noninnocent Dioxolene Ligand: Combined Experimental and ab Initio Study of [(3,5-di-tert-Bu2C6H2O2)ReCl3(OPPh3)]

02.07.2015 | Pavel A. Abramov; Nina P. Gritsan; Elizaveta A. Suturina; Artem S. Bogomyakov; Maxim N. Sokolov, Inorganic Chemistry, 2015

Reaction of [ReOCl3(PPh3)2] with 3,5-di-tert-butyl-1,2-benzoquinone (3,5-DTBQ) in hot toluene produces a new complex [(3,5-di-tert-Bu2C6H2O2)Re(OPPh3)Cl3] (1), which was isolated and characterized by elemental analysis, IR, UV–vis spectroscopy, and cyclic voltammetry. In order to clarify the ...

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Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant

02.07.2015 | Elizabeth A. Pedrick; Guang Wu; Trevor W. Hayton, Inorganic Chemistry, 2015

Reaction of [UVIO2(dppmo)2(OTf)][OTf] (dppmo = Ph2P(O)CH2P(O)Ph2) with 4 equiv of Ph3SiOTf and 2 equiv of Cp2Co generates the U(IV) complex UIV(OTf)4(dppmo)2 (1), as a yellow-green crystalline solid in 83% yield, along with Ph3SiOSiPh3 and [Cp2Co][OTf]. This reaction proceeds via a U(IV) ...

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Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal–Organic Framework

02.07.2015 | Honghan Fei; Matthew D. Sampson; Yeob Lee; Clifford P. Kubiak; Seth M. Cohen, Inorganic Chemistry, 2015

A manganese bipyridine complex, Mn(bpydc)(CO)3Br (bpydc = 5,5′-dicarboxylate-2,2′-bipyridine), has been incorporated into a highly robust Zr(IV)-based metal–organic framework (MOF) for use as a CO2 reduction photocatalyst. In conjunction with [Ru(dmb)3]2+ (dmb = 4,4′-dimethyl-2,2′-bipyridine) as ...

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Neutral “Cp-Free” Silyl-Lanthanide(II) Complexes: Synthesis, Structure, and Bonding Analysis

01.07.2015 | Rainer Zitz; Johann Hlina; Karl Gatterer; Christoph Marschner; Tibor Szilvási; Judith Baumgartner, Inorganic Chemistry, 2015

Complexes featuring lanthanide silicon bonds represent a research area still in its infancy. Herein, we report a series of Cp-free lanthanide (+II) complexes bearing σ-bonded silyl ligands. By reactions of LnI2 (Ln = Yb, Eu, Sm) either with a 1,4-oligosilanyl dianion ...

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Design and Characterization of Phosphine Iron Hydrides: Toward Hydrogen-Producing Catalysts

01.07.2015 | Katharina Weber; Thomas Weyhermüller; Eckhard Bill; Özlen F. Erdem; Wolfgang Lubitz, Inorganic Chemistry, 2015

Diamagnetic iron chloro compounds [(PPh2NPh2)FeCp*Cl] [1Cl] and [(PCy2NPh2)FeCp*Cl] [2Cl] and the corresponding hydrido complexes [(PPh2NPh2)FeCp*H] [1H] and [(PCy2NPh2)FeCp*H] [2H] have been synthesized and characterized by NMR spectroscopy, electrochemical studies, electronic absorption, and ...

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Organic–Inorganic Hybrid Materials Based on Basket-like {Ca⊂P6Mo18O73} Cages

01.07.2015 | He Zhang; Kai Yu; Jing-hua Lv; Li-hong Gong; Chun-mei Wang; Chun-xiao Wang; Di Sun; Bai-Bin Zhou, Inorganic Chemistry, 2015

Four basket-like organic–inorganic hybrids, formulated as [{CuII(H2O)2}{Ca4(H2O)4(HO0.5)3(en)2}{Ca⊂P6Mo4VMo14VIO73}]·7H2O (1), (H4bth)[{FeII(H2O)}{Ca⊂P6Mo18VIO73}]·4H2O (2), (H2bih)3[{CuII(H2O)2}{Ca⊂P6Mo2VMo16VIO73}]·2H2O (3), (H2bib)3[{FeII(H2O)2}{Ca⊂P6Mo2V Mo16VIO73}]·4H2O (4), (bth = ...

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Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

01.07.2015 | Yoshiaki Nishibayashi, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b00881

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New Family of Lanthanide-Based Complexes with Different Scorpionate-Type Ligands: A Rare Case Where Dysprosium and Ytterbium Analogues Display Single-Ion-Magnet Behavior

01.07.2015 | Anthony Lannes; Dominique Luneau, Inorganic Chemistry, 2015

A new family of lanthanide complexes [Ln(Tpz)2Bpz]·xCH2Cl2 (Ln = Gd, Tb, Dy, Ho, x = 0.5; Ln = Yb, x = 1; Tpz = hydrotris(pyrazolyl)borate; Bpz = dihydrobis(pyrazolyl)borate) has been synthesized. Those complexes have been characterized by single-crystal X-ray diffraction, and the magnetic ...

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Post-Assembly Covalent Di- and Tetracapping of a Dinuclear [Fe2L3]4+ Triple Helicate and Two [Fe4L6]8+ Tetrahedra Using Sequential Reductive Aminations

30.06.2015 | Christopher R. K. Glasson; George V. Meehan; Murray Davies; Cherie A. Motti; Jack K. Clegg; Leonard F. Lindoy, Inorganic Chemistry, 2015

The use of a highly efficient reductive amination procedure for the postsynthetic end-capping of metal-templated helicate and tetrahedral supramolecular structures bearing terminal aldehyde groups is reported. Metal template formation of a [Fe2L3]4+ dinuclear helicate and two [Fe4L6]8+ tetrahedra ...

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Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst

30.06.2015 | Matthew D. Sampson; Clifford P. Kubiak, Inorganic Chemistry, 2015

Earth-abundant manganese bipyridine complexes have been extensively studied as homogeneous electrocatalysts for proton-coupled CO2 reduction. To date, these manganese complexes have not been examined as catalysts for the reduction of other small molecules. We report electrocatalytic H2 production ...

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