05.04.2013 | A. Demont; D. Pelloquin; S. Hébert; M. Hervieu; J. Höwing; A. Maignan, Inorganic Chemistry, 2013

The oxycarbonate Sr7Co4(CO3)O11.36 exhibits a peculiar structure that has been characterized by combining transmission electron microscopy analyses and neutron diffraction. It consists of a regular intergrowth between the m = 2 and carbonated m = 3 members of the Srm+1ComO3m+1 ...

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05.04.2013 | Guiling Zhang; Kejuan Chen; Hui Chen; Jiannian Yao; Sason Shaik, Inorganic Chemistry, 2013

Mononuclear Ru-based water oxidation catalysts (WOCs) constitute an important class of WOCs for water splitting. This work constitutes a systematic study of Ru–O2 complexes of mononuclear ruthenium WOCs, with a focus on the thermodynamics of water-assisted O2 release in various electronic ...

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05.04.2013 | Rafaela A. L. Silva; Ana I. S. Neves; Elsa B. Lopes; Isabel C. Santos; Joana T. Coutinho; Laura C. J. Pereira; Conce ..., Inorganic Chemistry, 2013

The synthesis and characterization of (α-DT-TTF)2[Au(mnt)2] is reported. The magnetic properties of this new salt show that it is still a rare example of an organic spin-ladder. (α-DT-TTF)2[Au(mnt)2] shares the same ladder structure of the DT-TTF and ETT-TTF analogues, and its room ...

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05.04.2013 | Tetsuro Kusamoto; Hiroshi M. Yamamoto; Naoya Tajima; Yugo Oshima; Satoshi Yamashita; Reizo Kato, Inorganic Chemistry, 2013

Inorganic Chemistry DOI: 10.1021/ic400285a

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05.04.2013 | Bing-Ping Yang; Chun-Li Hu; Xiang Xu; Chao Huang; Jiang-Gao Mao, Inorganic Chemistry, 2013

The synthesis, crystal and electronic structures, and optical properties of the first zinc(II) vanadium(V) iodate, namely, Zn2(VO4)(IO3), are reported. Zn2(VO4)(IO3) crystallizes in the noncentrosymmetric (NCS) and polar space group Pc (No. 7) with a = 5.2714(8) Å, b = 10.0402(11) Å, c = ...

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05.04.2013 | Tanmay Banerjee; Sreejith Kaniyankandy; Amitava Das; Hirendra Nath Ghosh, Inorganic Chemistry, 2013

The synthesis of two new ruthenium(II)- and osmium(II)-polypyridyl complexes 3 and 4, respectively, with resorcinol as the enediol anchoring moiety, is described. Steady-state photochemical and electrochemical studies of the two sensitizer dyes confirm strong binding of the dyes to TiO2 in ...

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05.04.2013 | Nikhil Taxak; Bhargav Patel; Prasad V. Bharatam, Inorganic Chemistry, 2013

Carbene-heme-iron-porphyrin complexes generated from cytochrome P450 (CYP450)-mediated metabolism of compounds containing methylenedioxyphenyl (MDP) moiety lead to the mechanism-based inhibition (MBI) of CYPs. This coordination complex is termed as the metabolic-intermediate complex (MIC). ...

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05.04.2013 | Miguel A. Esteruelas; Montserrat Oliván; Andrea Vélez, Inorganic Chemistry, 2013

Treatment of the dimer [Rh(μ-Cl)(C8H14)2]2 (1a) with 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene [xant(PiPr2)2] leads to the d8 square-planar complex RhCl{xant(PiPr2)2} (2), whereas reaction of the iridium counterpart [Ir(μ-Cl)(C8H14)2]2 (1b) gives the d6 octahedral compound ...

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05.04.2013 | Mei Zhang; Wen-Juan Ma; Chun-Ting He; Long Jiang; Tong-Bu Lu, Inorganic Chemistry, 2013

The design and synthesis of chemosensors for the recognition of a certain nucleoside polyphosphate among various structurally similar nucleoside polyphosphates remain a fundamental challenge. Herein, we report the new fluorescent chemosensor [Zn2L](ClO4)4 (1; L = ...

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04.04.2013 | Vadapalli Chandrasekhar; Atanu Dey; Antonio J. Mota; Enrique Colacio, Inorganic Chemistry, 2013

The reaction of the multisite coordination ligand (LH4) with CoX2·nH2O in the presence of tetrabutylammonium hydroxide affords a series of homometallic dinuclear mixed-valence complexes, [CoIIICoII(LH2)2(X)(H2O)](H2O)m (1, X = Cl and m = 4; 2, X = Br and m = 4; 3, X = NO3 and m = 3). All of ...

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