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9.550 Aktuelle Fachpublikationen in Inorganic Chemistry


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Ullmann Reaction Catalyzed by Heterogeneous Mesoporous Copper/Manganese Oxide: A Kinetic and Mechanistic Analysis

11.08.2017 | Kankana Mullick; Sourav Biswas; Chiho Kim; Ramamurthy Ramprasad; Alfredo M. Angeles-Boza; Steven L. Suib, Inorganic Chemistry, 2017

A heterogeneous copper oxide supported on mesoporous manganese oxide (meso Cu/MnOx) was explored for Ullmann-type cross-coupling reactions. An inverse micelle-templated evaporation-induced self-assembly method with in situ addition of copper was adopted to synthesize the mesoporous catalyst. ...


The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors

10.08.2017 | Wenge Xiao; Dan Wu; Liangliang Zhang; Xia Zhang; Zhendong Hao; Guo-Hui Pan; Ligong Zhang; Xuewei Ba; Jiahua Zhang, Inorganic Chemistry, 2017

Forming solid solutions through cation substitution is an efficient way to improve the luminescence properties of Ce3+ or Eu2+ activated phosphors and even to develop new ones, which is badly needed for phosphor-converted white LEDs. Here, we report new color tunable solid solution phosphors ...


Covalent Synthesis of Two Hybrids Composed of Dawson-Type Polyoxometalate and Porphyrin with Remarkable Third-Order Optical Nonlinearities Reflecting the Effect of Polyoxometalates

10.08.2017 | Hafiz Muhammad Asif; Yunshan Zhou; Lijuan Zhang; Nusrat Shaheen; Di Yang; Jiaqi Li; Yi Long; Arshad Iqbal; Yanqin Li, Inorganic Chemistry, 2017

Two new porphyrin-polyoxometalate hybrids, namely, [(C4H9)4N]10H2[{COHNC(CH2O)3P2V3W15O59}2C44N4H28]·CH3CN 1, bearing two covalent-bonded Wells–Dawson-type polyoxometalates (POMs), and [(C4H9)4N)]5H[COHNC(CH2O)3P2V3W15O59{C44H29N4}]·CH3CN 2, bearing one covalent-bonded POM, have been synthesized ...


Achieving High Performances of Nondoped OLEDs Using Carbazole and Diphenylphosphoryl-Functionalized Ir(III) Complexes as Active Components

10.08.2017 | Hui-Ting Mao; Chun-Xiu Zang; Guo-Gang Shan; Hai-Zhu Sun; Wen-Fa Xie; Zhong-Min Su, Inorganic Chemistry, 2017

Nondoped electroluminescent devices offer advantages over their doped counterparts such as good reproducibility, reduced phase separation between host and guest materials, and potential of lower-cost devices. However, low luminance efficiencies and significant roll-off values are longstanding ...


Phase Composition, Density, and Ionic Conductivity of the Li7La3Zr2O12-Based Composites with LiPO3 Glass Addition

10.08.2017 | Svetlana V. Pershina; Eugenia A. Il’ina; Olga G. Reznitskikh, Inorganic Chemistry, 2017

The glass-ceramic composite electrolytes based on tetragonal Li7La3Zr2O12 (t-LLZ) and cubic Al-doped Li7La3Zr2O12 (c-LLZ) with the LiPO3 glass additive have been prepared. The electrical conductivity and microstructure of the t-LLZ/LiPO3 and c-LLZ/LiPO3 composites have been investigated. The ...


Toolbox of Nonmetallocene Lanthanides: Multifunctional Catalysts in Group-Transfer Polymerization

10.08.2017 | Friederike Adams; Martin R. Machat; Peter T. Altenbuchner; Johannes Ehrmaier; Alexander Pöthig; Tolga N. V. Karsili; ..., Inorganic Chemistry, 2017

Herein, we present a fundamental study of isostructural 2-methoxyethylamino-bis(phenolate)-lanthanide complexes [(ONOO)RM(X)(THF)] (M = Lu, Y; R = tBu, CMe2Ph, X = CH2TMS, collidine; THF = tetrahydrofuran; TMS = trimethylsilyl) for rare-earth metal-mediated group-transfer polymerization (GTP). ...


Ligand Configuration-Induced Manganese(II) Coordination Polymers: Syntheses, Crystal Structures, Sorption, and Magnetic Properties

10.08.2017 | Wen-Juan Shi; Li-Yun Du; Hong-Yun Yang; Kun Zhang; Lei Hou; Yao-Yu Wang, Inorganic Chemistry, 2017

Three new coordination polymers, {[Mn3(pzbtz)2(Cl)2(H2O)2]·4H2O}n (1), {Mn2(pzbtz)(SO4)(H2O)3]·3H2O}n (2), and {[Mn3(pzbtz)3(H2O)3]·1.5DMA·2H2O}n (3), have been solvothermally synthesized with MnCl2/MnSO4 and a bitriazole ligand, 5′-(pyrazin-2-yl)-2H,4′H-3,3′-bi(1,2,4-triazole) (H2pzbtz), in ...


Sky Blue-Emitting Iridium(III) Complexes Bearing Nonplanar Tetradentate Chromophore and Bidentate Ancillary

10.08.2017 | Yu-Sian Li; Jia-Ling Liao; Ke-Ting Lin; Wen-Yi Hung; Shih-Hung Liu; Gene-Hsiang Lee; Pi-Tai Chou; Yun Chi, Inorganic Chemistry, 2017

Tetradentate chelates bearing tripodal arranged terpyridine and a functional pyrazole unit (i.e., L1-H and L2-H) were employed in preparation of Ir(III) complexes [Ir(L1)Cl2] (1) and [Ir(L2)Cl2] (2); subsequent chloride-to-bipyrazolate substitution gave [Ir(L1)(bipz)] (3) and [Ir(L2)(bipz)] (4). ...


Crystal Growth and Characterization of HgBa2Ca2Cu3O8+δ Superconductors with the Highest Critical Temperature at Ambient Pressure

10.08.2017 | Bastien Loret; Anne Forget; Jean-Baptiste Moussy; Sylvie Poissonnet; Patrick Bonnaillie; Gaston Collin; Pierre Thuér ..., Inorganic Chemistry, 2017

We report an original procedure for the elaboration of very high-quality single crystals of superconducting HgBa2Ca2Cu3O8+δ mercury cuprates. These single crystals are unique, with very high-quality surface paving the way for spectroscopic, transport, and thermodynamic probes in order to ...


Structural and Morphological Description of Sn/SnOx Core–Shell Nanoparticles Synthesized and Isolated from Ionic Liquid

10.08.2017 | Nadia Soulmi; Damien Dambournet; Cécile Rizzi; Juliette Sirieix-Plénet; Mathieu Duttine; Alain Wattiaux; Jolanta Swi ..., Inorganic Chemistry, 2017

The potential application of high capacity Sn-based electrode materials for energy storage, particularly in rechargeable batteries, has led to extensive research activities. In this scope, the development of an innovative synthesis route allowing to downsize particles to the nanoscale is of ...


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