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9.104 Aktuelle Fachpublikationen in Inorganic Chemistry


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Tin(IV) Compounds with 2-C6F4PPh2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin–Palladium Complexes via Oxidative Addition

13.04.2017 | Erik Wächtler; Sven Wahlicht; Steven H. Privér; Martin A. Bennett; Birgit Gerke; Rainer Pöttgen; Erica Brendler; Rob ..., Inorganic Chemistry, 2017

The tin(IV) compounds MexSn(2-C6F4PPh2)4–x (1, x = 1; 2, x = 2) and ClSn(2-C6F4PPh2)3 (3) were obtained from the reactions of 2-LiC6F4PPh2 with MeSnCl3 (3:1), Me2SnCl2 (2:1), or SnCl4 (3:1), respectively. The reactions of 2-LiC6F4PPh2 with SnCl4 in different stoichiometric ratios (4:1–1:1) gave 3 ...


Spectroscopic Investigation of Up-Conversion Properties in Green Emitting BaMgF4:Yb3+,Tb3+ Phosphor

13.04.2017 | Bhushan P. Kore; Ashwini Kumar; Anurag Pandey; Robin E. Kroon; Jacobus J. Terblans; Sanjay J. Dhoble; Hendrik C. Swart, Inorganic Chemistry, 2017

In this work we have comprehensively studied the up-conversion (UC) properties of BaMgF4:Yb3+,Tb3+ phosphor for the first time. BaMgF4:Yb3+,Tb3+ phosphors were prepared by a simple and low cost precipitation method. To determine the influence of dopant concentration on luminescence properties, ...


Impact of Halogenido Coligands on Magnetic Anisotropy in Seven-Coordinate Co(II) Complexes

13.04.2017 | Bohuslav Drahoš; Radovan Herchel; Zdeněk Trávníček, Inorganic Chemistry, 2017

The structural and magnetic features of a series of mononuclear seven-coordinate CoII complexes with the general formula [Co(L)X2], where L is a 15-membered pyridine-based macrocyclic ligand (3,12,18-triaza-6,9-dioxabicyclo[12.3.1]octadeca-1(18),14,16-triene) and X = Cl– (1), Br– (2), or I– (3), ...


Large Positive Thermal Expansion and Small Band Gap in Double-ReO3-Type Compound NaSbF6

13.04.2017 | C. Yang; B. Y. Qu; S. S. Pan; L. Zhang; R. R. Zhang; P. Tong; R. C. Xiao; J. C. Lin; X. G. Guo; K. Zhang; H. Y. Tong ..., Inorganic Chemistry, 2017

Double-ReO3-type structure compound NaSbF6 undergoes a low-temperature rhombohedral to high-temperature cubic phase between 303 and 323 K, as revealed by temperature-dependent X-ray diffractions. Although many double-ReO3-type fluorides exhibit either low thermal expansion or negative thermal ...


The Role of Structural and Compositional Heterogeneities in the Insulator-to-Metal Transition in Hole-Doped APd3O4 (A = Ca, Sr)

13.04.2017 | Leo K. Lamontagne; Geneva Laurita; Michael Knight; Huma Yusuf; Jerry Hu; Ram Seshadri; Katharine Page, Inorganic Chemistry, 2017

The cubic semiconducting compounds APd3O4 (A = Ca, Sr) can be hole-doped by Na substitution on the A site and driven toward more conducting states. This process has been followed here by a number of experimental techniques to understand the evolution of electronic properties. While an ...


Excimer–Monomer Photoluminescence Mechanochromism and Vapochromism of Pentiptycene-Containing Cyclometalated Platinum(II) Complexes

13.04.2017 | Che-Jen Lin; Yi-Hung Liu; Shie-Ming Peng; Teruo Shinmyozu; Jye-Shane Yang, Inorganic Chemistry, 2017

The ability of the bulky H-shaped pentiptycene scaffold in promoting the mechanochromic and vapochromic luminescence properties for organometallic materials has been demonstrated with the N^C^N cyclometalated platinum(II) complexes [X-NCNPtY], where X = Br or Pa, the substituent on the terdentate ...


Ferromagnetic Exchange in Bichloride Bridged Cu(II) Chains: Magnetostructural Correlations between Ordered and Disordered Systems

13.04.2017 | Susan N. Herringer; Christopher P. Landee; Mark M. Turnbull; Jordi Ribas-Ariño; Juan J. Novoa; Matthew Polson; Jan L ..., Inorganic Chemistry, 2017

The synthesis, structure, magnetic properties, and theoretical analysis of a new phase of dichloro(2-chloro-3-methylpyridine)copper(II) (2) and its isomorphous analogue dichloro(2-bromo-3-methylpyridine)copper(II) (3) are reported. Both complexes crystallize in the orthorhombic space group Pbca ...


Self-Assembled Upconversion Nanoparticle Clusters for NIR-controlled Drug Release and Synergistic Therapy after Conjugation with Gold Nanoparticles

12.04.2017 | Huijuan Cai; Tingting Shen; Alexander M. Kirillov; Yu Zhang; Changfu Shan; Xiang Li; Weisheng Liu; Yu Tang, Inorganic Chemistry, 2017

Fabricated three-dimensional (3D) upconversion nanoclusters (abbreviated as EBSUCNPs) are obtained via an emulsion-based bottom-up self-assembly of NaGdF4:Yb/Er@NaGdF4 nanoparticles (abbreviated as UCNPs), which comprise a NaGdF4:Yb/Er core and a NaGdF4 shell. The EBSUCNPs were then coated with a ...


Self-Assembly of Extended Head-to-Tail Triangular Pt3 Macrocycles into Nanotubes

12.04.2017 | Zhengyu Chen; Brian J. Sahli; Mark J. MacLachlan, Inorganic Chemistry, 2017

New pyridylsalicylaldimine-based ligands with extended conjugation have been synthesized. The reaction of these ligands with K2PtCl4 yielded triangular Pt3 macrocycles rather than the anticipated Pt4 macrocycles. The macrocycles have been analyzed in solution by variable-temperature and ...


BaAu2S2: A Au-Based Intrinsic Photocatalyst for High-Performance Visible-Light Photocatalysis

12.04.2017 | Molin Zhou; Xin Jiang; Xingxing Jiang; Ke Xiao; Yangwu Guo; Hongwei Huang; Zheshuai Lin; Jiyong Yao; Chen-Ho Tung; L ..., Inorganic Chemistry, 2017

A new Au-based sulfide BaAu2S2 was obtained through solid-state reaction. It crystallizes in the tetragonal space group I41/amd with unit cell parameters of a = 6.389 72(2) Å, b = 6.389 72(2) Å, c = 12.7872(1) Å, and Z = 4. Its structure features [AuS2/2]∞ zigzag chains composed of corner-sharing ...


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