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7.074 Aktuelle Fachpublikationen in Inorganic Chemistry


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Rapid Microwave-Assisted Solvothermal Synthesis of Non-Olivine Cmcm Polymorphs of LiMPO4 (M = Mn, Fe, Co, and Ni) at Low Temperature and Pressure

02.10.2015 | Gaurav Assat; Arumugam Manthiram, Inorganic Chemistry, 2015

Lithium transition-metal phosphates, LiMPO4 (M = Mn, Fe, Co, and Ni), have attracted significant research interest over the past two decades as an important class of lithium ion battery cathode materials. However, almost all of the investigations thus far have focused on the olivine polymorph ...


Pressure-Induced Structures and Properties in Indium Hydrides

02.10.2015 | Yunxian Liu; Defang Duan; Fubo Tian; Hanyu Liu; Chao Wang; Xiaoli Huang; Da Li; Yanbin Ma; Bingbing Liu; Tian Cui, Inorganic Chemistry, 2015

The structures, electron properties, and potential superconductivity of indium hydrides are systematically studied under high pressure by first-principles density functional calculations. Upon compression, two stable stoichiometries (InH3 and InH5) are predicted to be thermodynamically stable. ...


Structural, Optical, and Electrical Characterization of Yttrium-Substituted BiFeO3 Ceramics Prepared by Mechanical Activation

02.10.2015 | Antonio Perejón; Eva Gil-González; Pedro E. Sánchez-Jiménez; José M. Criado; Luis A. Pérez-Maqueda, Inorganic Chemistry, 2015

Ceramics of Bi1–xYxFeO3 solid solutions (x = 0.02, 0.07, and 0.10) have been prepared by mechanical activation followed by sintering. The effect of yttrium content on the structural, electrical, and optical properties of the materials has been studied. Thus, single-phase solid solutions with ...


Controlling the Fluorescence Response of PET Sensors via the Metal-Ion π-Contacting Ability of the Fluorophore: Coumarin, a Weaker π Contacter

01.10.2015 | Joseph W. Nugent; Joseph H. Reibenspies; Robert D. Hancock, Inorganic Chemistry, 2015

The π-contact hypothesis, that quenching of the fluorescence of complexes of photoinduced electron transfer sensors with heavy diamagnetic metal ions may be caused by π contacts between the metal ion and the fluorophore of the sensor, is examined with a study of the fluorescent properties of the ...


Amidinate-Stabilized Group 9 Metal–Silicon(I) Dimer and −Silylene Complexes

01.10.2015 | Sabrina Khoo; Hui-Xian Yeong; Yongxin Li; Rakesh Ganguly; Cheuk-Wai So, Inorganic Chemistry, 2015

The coordination chemistry of the amidinate-stabilized silicon(I) dimer toward group 9 metal complexes is described. The reaction of [LSi:]2 (1, L = PhC(NtBu)2) with [Ir(cod)Cl]2 (cod = 1,5-cyclooctadiene) in toluene at ambient temperature afforded the base-stabilized silicon(I) dimer-iridium ...


Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site

30.09.2015 | Geoffrey M. Chambers; Mioy T. Huynh; Yulong Li; Sharon Hammes-Schiffer; Thomas B. Rauchfuss; Edward Reijerse; Wolfga ..., Inorganic Chemistry, 2015

A new class of synthetic models for the active site of [NiFe]-hydrogenases are described. The NiI/II(SCys)2 and FeII(CN)2CO sites are represented with (RC5H4)NiI/II and FeII(diphos)(CO) modules, where diphos = 1,2-C2H4(PPh2)2(dppe) or cis-1,2-C2H2(PPh2)2(dppv). The two bridging thiolate ligands ...


Donor Properties of a New Class of Guanidinate Ligands Possessing Ketimine Backbones: A Comparative Study Using Iron

30.09.2015 | Arnab K. Maity; Alejandro J. Metta-Magaña; Skye Fortier, Inorganic Chemistry, 2015

Addition of 1 equiv of LiN═CtBu2 or LiN═Ad (Ad = 2-adamantyl) to the aryl carbodiimide C(NDipp)2 (Dipp = 2,6-diisopropylphenyl) readily generates the lithium ketimine-guanidinates Li(THF)2[(X)C(NDipp)2] (X = N═CtBu2 (1-tBu), N═Ad (1-Ad)) in excellent yields. These new ligands can be readily ...


Sc2O@C2v(5)-C80: Dimetallic Oxide Cluster Inside a C80 Fullerene Cage

30.09.2015 | Qiangqiang Tang; Laura Abella; Yajuan Hao; Xiaohong Li; Yingbo Wan; Antonio Rodríguez-Fortea; Josep M. Poblet; Lai F ..., Inorganic Chemistry, 2015

A new oxide cluster fullerene, Sc2O@C2v(5)-C80, has been isolated and characterized by mass spectrometry, UV–vis–NIR absorption spectroscopy, cyclic voltammetry, 45Sc NMR, DFT calculations, and single crystal X-ray diffraction. The crystallographic analysis unambiguously elucidated that the cage ...


Ba2AsGaSe5: A New Quaternary Selenide with the Novel [AsGaSe5]4– Cluster and Interesting Photocatalytic Properties

29.09.2015 | Chao Li; Xiaoshuang Li; Hongwei Huang; Jiyong Yao; Yicheng Wu, Inorganic Chemistry, 2015

The new zero-dimensional selenide Ba2AsGaSe5 was synthesized via a solid-state reaction at 900 °C. It belongs to the orthorhombic space group Pnma with a = 12.632(3) Å, b = 8.9726(18) Å, c = 9.2029(18) Å, and Z = 4. In the structure, the As atom adopts trigonal-pyramidal coordination owing to the ...


Crystallographic, Electronic, and Magnetic Properties of Rock Salt Superstructure Sulfide Lu2CrS4 with Jahn–Teller Distortion

29.09.2015 | Keitaro Tezuka; Makoto Wakeshima; Masataka Nozawa; Keita Oshikane; Kenji Ohoyama; Yue Jin Shan; Hideo Imoto; Yukio H ..., Inorganic Chemistry, 2015

A new chromium(II) sulfide, Lu2CrS4, with a novel structure was prepared by a solid-state reaction. The powder X-ray diffraction pattern could be indexed as a tetragonal system, with a = 7.46373(2) Å, c = 22.6338(2) Å, and space group I4̅2d (No. 122). Rietveld analysis of the pattern provided the ...


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