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9.413 Aktuelle Fachpublikationen in Inorganic Chemistry


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Modulation of the Emission Mode of a Pt(II) Complex via Intermolecular Interactions

14.07.2017 | Junpei Kuwabara; Kaho Yamaguchi; Kazuma Yamawaki; Takeshi Yasuda; Yoshinobu Nishimura; Takaki Kanbara, Inorganic Chemistry, 2017

Compounds with controllable color emissions are potentially useful as photoluminescent materials in imaging and sensing applications. Multimolecular emission can be used realizing variable-color emitters and has been demonstrated in the solid state. However, achieving multimolecular emission in ...


Comprehension of the Effect of a Hydroxyl Group in Ancillary Ligand on Phosphorescent Property for Heteroleptic Ir(III) Complexes: A Computational Study Using Quantitative Prediction

14.07.2017 | Xiaolin Wang; Huiqing Yang; Yaping Wen; Li Wang; Junfeng Li; Jinglai Zhang, Inorganic Chemistry, 2017

A new Ir(III) complex (dfpypya)2Ir(pic–OH) (2) is theoretically designed by introduction of a simple hydroxyl group into the ancillary ligand on the basis of (dfpypya)2Ir(pic) (1) with the aim to get the high-efficiency and stable blue-emitting phosphors, where dfpypya is ...


Redox Interconversion of Non-Oxido Vanadium Complexes Accompanied by Acid–Base Chemistry of Thiol and Thiolate

14.07.2017 | Jyun-An Yan; Yu-Sen Chen; Ya-Ho Chang; Cheng-Yun Tsai; Chiao-Ling Lyu; Chun-Gang Luo; Gene-Hsiang Lee; Hua-Fen Hsu, Inorganic Chemistry, 2017

The redox nature of the non-oxido vanadium sulfur center is associated with several biological systems such as vanadium nitrogenase, the reduction of vanadium ion in ascidians, and the function of amavadin, which is a vanadium(IV) natural product contained in Amanita mushrooms. But the related ...


Methane Activations by Titanium Neopentylidene Complexes: Electronic Resilience and Steric Control

14.07.2017 | Dragan B. Ninković; Salvador Moncho; Predrag V. Petrović; Snežana D. Zarić; Michael B. Hall; Edward N. Brothers, Inorganic Chemistry, 2017

The titanium neopentylidene complex (PNP)Ti═CHtBu(CH2tBu) (PNP = N[2-PiPr2-4-methylphenyl]2–) is capable of activating both sp2 and sp3 C–H bonds under mild conditions. In addition to methane C–H activation, competition between the initial hydrogen abstraction reaction to form the methane ...


Ab Initio Ligand-Field Theory Analysis and Covalency Trends in Actinide and Lanthanide Free Ions and Octahedral Complexes

14.07.2017 | Julie Jung; Mihail Atanasov; Frank Neese, Inorganic Chemistry, 2017

Actinide chemistry is gaining increased focus in modern research, particularly in the fields of energy research and molecular magnetism. However, the structure–function and structure–property relationships of actinides have still not been studied as intensely as those for transition metals. In ...


Structural Investigation of Chemiresistive Sensing Mechanism in Redox-Active Porous Coordination Network

13.07.2017 | Jaejun Kim; Jin Young Koo; Yoon Ho Lee; Tatsuhiro Kojima; Yumi Yakiyama; Hiroyoshi Ohtsu; Joon Hak Oh; Masaki Kawano, Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b01165


Linear, Hypervalent Se34– Units and Unprecedented Cu4Se9 Building Blocks in the Copper(I) Selenide Ba4Cu8Se13

13.07.2017 | Stefan Maier; Olivier Perez; Denis Pelloquin; David Berthebaud; Sylvie Hébert; Franck Gascoin, Inorganic Chemistry, 2017

Single-crystal and polycrystalline Ba4Cu8Se13 were synthesized; the average crystal structure was solved by single-crystal X-ray diffraction, and the structural model was confirmed by a detailed electron microscopy study of polycrystalline Ba4Cu8Se13. The title compound can be rationalized as ...


Local Environment of Terbium(III) Ions in Layered Nanocrystalline Zirconium(IV) Phosphonate–Phosphate Ion Exchange Materials

13.07.2017 | Maxwell W. Terban; Chenyang Shi; Rita Silbernagel; Abraham Clearfield; Simon J. L. Billinge, Inorganic Chemistry, 2017

The structures of Zr(IV) phosphonate-phosphate based, unconventional metal organic framework materials have been determined using atomic pair distribution function analysis of high energy, X-ray total scattering diffraction data. They are found to form as nanocrystalline layers of Zr phosphate, ...


Chiral Resolution of Lanthanoid Cryptates with Extreme Configurational Stability

12.07.2017 | Elisabeth Kreidt; Carolin Dee; Michael Seitz, Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b01407


Improvement of Green Upconversion Monochromaticity by Doping Eu3+ in Lu2O3:Yb3+/Ho3+ Powders with Detailed Investigation of the Energy Transfer Mechanism

12.07.2017 | Guotao Xiang; Yan Ma; Wen Liu; Sha Jiang; Xiaobing Luo; Li Li; Xianju Zhou; Zhiwei Gu; Jiapeng Wang; Yongshi Luo; Ji ..., Inorganic Chemistry, 2017

The monochromaticity improvement of green upconversion (UC) in Lu2O3:Yb3+/Ho3+ powders has been successfully realized by tridoping Eu3+. The integral area ratio of green emission to red emission of Ho3+ increases 4.3 times with increasing Eu3+ doping concentration from 0 to 20 mol %. The energy ...


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