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6.448 Aktuelle Fachpublikationen in Inorganic Chemistry


Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex

22.04.2015 | Anna Lewandowska-Andralojc; Teera Baine; Xuan Zhao; James T. Muckerman; Etsuko Fujita; Dmitry E. Polyansky, Inorganic Chemistry, 2015

The ability of cobalt-based transition metal complexes to catalyze electrochemical proton reduction to produce molecular hydrogen has resulted in a large number of mechanistic studies involving various cobalt complexes. While the basic mechanism of proton reduction promoted by cobalt species is ...


Cation-Exchange Porosity Tuning in a Dynamic 4d–4f–3d Framework for NiII Ion-Selective Luminescent Probe

17.04.2015 | Ying Wang; Xiu-Guang Wang; Bin Yuan; Cheng-Yuan Shao; Yuan-Yuan Chen; Bing-Bing Zhou; Ming-Shu Li; Xiao-Mai An; Peng ..., Inorganic Chemistry, 2015

A heterometallic complex {[Yb2(L)6Cd2][Cd(H2O)6]·6H2O}n (Yb–Cd) (H2L = oxidiacetic acid) was synthesized under hydrothermal conditions. In Yb–Cd, each L chelates to one Yb3+ center and bonds to two Cd2+ ions in an anti-anti configuration. Yb and Cd atoms are arrayed alternatively and connected by ...


Structure–Function Relationships for Electrocatalytic Water Oxidation by Molecular [Mn12O12] Clusters

17.04.2015 | Yong Yan; John S. Lee; Daniel A. Ruddy, Inorganic Chemistry, 2015

A series of Mn12O12(OAc)16–xLx(H2O)4 molecular clusters (L = acetate, benzoate, benzenesulfonate, diphenylphosphonate, dichloroacetate) were electrocatalytically investigated as water oxidation electrocatalysts on a fluorine-doped tin oxide glass electrode. Four of the [Mn12O12] compounds ...


Binding Studies of G-Quadruplex DNA and Porphyrins: Cu(T4) vs Sterically Friendly Cu(tD4)

17.04.2015 | Abby J. Gaier; David R. McMillin, Inorganic Chemistry, 2015

This investigation explores binding interactions involving G-quadruplex DNA and two copper(II)-containing porphyrins (5,10,15,20-tetra(N-methylpyridinium-4-yl)porphyrinato)copper(II) and the sterically friendlier analogue (trans-5,15-di(N-methylpyridinium-4-yl)porphyrinato)copper(II), or Cu(T4) ...


Intramolecular Ferromagnetic Radical–CuII Coupling in a CuII Complex Ligated with Pyridyl-Substituted Triarylmethyl Radicals

17.04.2015 | Tetsuro Kusamoto; Yohei Hattori; Akira Tanushi; Hiroshi Nishihara, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b00499


Formation and Transmetalation Mechanisms of Homo- and Heterometallic (Fe/Zn) Trinuclear Triple-Stranded Side-by-Side Helicates

16.04.2015 | Bidyut Akhuli; Luca Cera; Barun Jana; Subrata Saha; Christoph A. Schalley; Pradyut Ghosh, Inorganic Chemistry, 2015

A novel linear hybrid tris-bidentate neutral ligand having 2,2′-bipyridine and two terminal triazolylpyridine coordination sites (L) was efficiently synthesized and explored in the synthesis of trinuclear triple-stranded homometallic side-by-side helicates L3Fe3(OTf)6 (1) and L3Zn3(OTf)6 (2), in ...


Novel Microporous Metal–Organic Framework Exhibiting High Acetylene and Methane Storage Capacities

15.04.2015 | Xing Duan; Chuande Wu; Shengchang Xiang; Wei Zhou; Taner Yildirim; Yuanjing Cui; Yu Yang; Banglin Chen; Guodong Qian, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.5b00194


Corrole-BODIPY Dyads: Synthesis, Structure, and Electrochemical and Photophysical Properties

15.04.2015 | Biju Basumatary; Adiki Raja Sekhar; R. V. Ramana Reddy; Jeyaraman Sankar, Inorganic Chemistry, 2015

A free-base and its Cu(III) derivative of bichromophoric meso-β linked corrole-BODIPY dyad were synthesized and structurally characterized by single crystal X-ray diffraction (XRD). Both corrole and BODIPY fragments maintained respective ground state electronic isolation despite their connection ...


Electronic and Steric Influences of Pendant Amine Groups on the Protonation of Molybdenum Bis(dinitrogen) Complexes

14.04.2015 | Liezel A. Labios; Zachariah M. Heiden; Michael T. Mock, Inorganic Chemistry, 2015

The synthesis of a series of PEtPNRR′ (PEtPNRR′ = Et2PCH2CH2P(CH2NRR′)2, R = H, R′ = Ph or 2,4-difluorophenyl; R = R′ = Ph or iPr) diphosphine ligands containing mono- and disubstituted pendant amine groups and the preparation of their corresponding molybdenum bis(dinitrogen) complexes ...


C–F Bond Activation by Transient Phosphenium Dications

14.04.2015 | Nemanja Đorđević; Madelyn Qin Yi Tay; Senthilkumar Muthaiah; Rakesh Ganguly; Dušan Dimić; Dragoslav Vidović, Inorganic Chemistry, 2015

Inorganic Chemistry DOI: 10.1021/ic5031125


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