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9.055 Aktuelle Fachpublikationen in Inorganic Chemistry


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Covalent Metal–Metal-Bonded Mn4 Tetrahedron Inscribed within a Four-Coordinate Manganese Cubane Cluster, As Evidenced by Unexpected Temperature-Independent Diamagnetism

17.03.2017 | Shivaiah Vaddypally; Daniel J. Jovinelli; Ian G. McKendry; Michael J. Zdilla, Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b00152


Room-Temperature Magneto-dielectric Effect in LaGa0.7Fe0.3O3+γ; Origin and Impact of Excess Oxygen

17.03.2017 | Hari Mohan Rai; Preetam Singh; Shailendra K. Saxena; Vikash Mishra; M. Kamal Warshi; Rajesh Kumar; Parasmani Rajput; ..., Inorganic Chemistry, 2017

We report an observation of room-temperature magneto-dielectric (RTMD) effect in LaGa0.7Fe0.3O3+γ compound. The contribution of intrinsic/resistive sources in the presently observed RTMD effect was analyzed by measuring direct-current (dc) magnetoresistance (MR) in four-probe geometry and ...


Pentanuclear Lanthanide Mono-organophosphates: Synthesis, Structure, and Magnetism

17.03.2017 | Sandeep K. Gupta; Stuart K. Langley; Kamna Sharma; Keith S. Murray; Ramaswamy Murugavel, Inorganic Chemistry, 2017

Research on rare-earth phosphates has recently received substantial interest because of their unique physical and chemical properties. In recent years, because of their low solubility, research interest has been built on developing methodologies to prepare nanostructures and grow single crystals ...


Two Finite Binuclear [M2(μ2-OH)(COO)2] (M = Co, Ni) Based Highly Porous Metal–Organic Frameworks with High Performance for Gas Sorption and Separation

17.03.2017 | Jiantang Li; Xiaolong Luo; Nian Zhao; Lirong Zhang; Qisheng Huo; Yunling Liu, Inorganic Chemistry, 2017

Two highly porous MOFs, [Co2(μ2-OH)(bpdc)(Htpim)2][SiF6]·3.5DMA·2.5CH3OH (JLU-Liu37, H2bpdc = biphenyl-4,4′-dicarboxylate, Htpim = 2,4,5-tri(4-pyridyl)imidazole) and [Ni2(μ2-OH)(bpdc)(Htpim)2][SiF6]·7.5DMA·6CH3OH (JLU-Liu38), have been solvothermally synthesized by using the mixed ligand ...


Effect of the Cation Distribution and Microstructure on the Magnetic Behavior of the CoMn2O4 Oxide

17.03.2017 | Jasminka Popović; Marijana Jurić; Damir Pajić; Martina Vrankić; Janez Zavašnik; Jelena Habjanič, Inorganic Chemistry, 2017

The sizes of CoMn2O4 nanoparticles can easily be tuned, from 40 to 8 nm, depending on the temperature of decomposition of the single-source molecular precursor {[Co(bpy)3][Mn2(C2O4)3]·H2O}n. The structural features of the CoMn2O4 spinel are also affected by the heat treatment temperature, showing ...


Syntheses, Photoluminescence, and Electroluminescence of a Series of Sublimable Bipolar Cationic Cuprous Complexes with Thermally Activated Delayed Fluorescence

17.03.2017 | Fuli Zhang; Yuqiao Guan; Xulin Chen; Shuangshuang Wang; Dong Liang; Yafei Feng; Shufen Chen; Suzhi Li; Zhongyi Li; F ..., Inorganic Chemistry, 2017

Three thermally activated delayed fluorescence cationic cuprous complexes [Cu(POP) (ECAF)]PF6 (1, POP = bis(2-diphenylphosphinophenyl)ether, ECAF = 9,9-bis(9-ethylcarbazol-3-yl)-4,5-diazafluorene), [Cu(POP) (EHCAF)]PF6 (2, EHCAF = 9,9-bis(9-ethylhexylcarbazol-3-yl)-4,5-diazafluorene), and ...


Temperature Sensing Using Thermal Population of Low-Lying Energy Levels with (Sm0.01Gd0.99)VO4

17.03.2017 | Jiajia Cai; Lu Zhao; Fangfang Hu; Xiantao Wei; Yonghu Chen; Min Yin; Chang-Kui Duan, Inorganic Chemistry, 2017

A temperature sensing scheme is proposed that is based on the dramatic temperature dependence of the photoluminescence when Sm3+ dopants are excited from thermally populated 6H7/2,9/2 levels, rather than the ground level 6H5/2, to the 4G5/2 luminescent level. The scheme has the advantage of ...


Synthesis and Photobiological Activity of Ru(II) Dyads Derived from Pyrrole-2-carboxylate Thionoesters

16.03.2017 | Deborah A. Smithen; Huimin Yin; Michael H. R. Beh; Marc Hetu; T. Stanley Cameron; Sherri A. McFarland; Alison Thompson, Inorganic Chemistry, 2017

The synthesis and characterization of a series of heteroleptic ruthenium(II) dyads derived from pyrrole-2-carboxylate thionoesters are reported. Ligands bearing a conjugated thiocarbonyl group were found to be more reactive toward Ru(II) complexation compared to analogous all-oxygen ...


Preparation of Ammonium-Functionalized Polyhedral Oligomeric Silsesquioxanes with High Proportions of Cagelike Decamer and Their Facile Separation

16.03.2017 | Kenta Imai; Yoshiro Kaneko, Inorganic Chemistry, 2017

In this study, we found that ammonium-functionalized polyhedral oligomeric silsesquioxanes (POSSs; 2Am-POSS and Am-POSS) with high proportions of cagelike decamer (T10-POSS; 54% and 45%, estimated from 29Si NMR spectra) could be successfully prepared by the hydrolytic condensation of ...


Pressure-Stabilized Superconductive Ionic Tantalum Hydrides

16.03.2017 | Quan Zhuang; Xilian Jin; Tian Cui; Yanbin Ma; Qianqian Lv; Ying Li; Huadi Zhang; Xing Meng; Kuo Bao, Inorganic Chemistry, 2017

High-pressure structures of tantalum hydrides were investigated over a wide pressure range of 0–300 GPa by utilizing evolutionary structure searches. TaH and TaH2 were found to be thermodynamically stable over this entire pressure range, whereas TaH3, TaH4, and TaH6 become thermodynamically ...


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