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7.860 Aktuelle Fachpublikationen in Inorganic Chemistry

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FeII Spin Transition Materials Including an Amino–Ester 1,2,4-Triazole Derivative, Operating at, below, and above Room Temperature

22.04.2016 | Marinela M. Dîrtu; Anil D. Naik; Aurelian Rotaru; Leonard Spinu; Dirk Poelman; Yann Garcia, Inorganic Chemistry, 2016

A new family of one-dimensional FeII 1,2,4-triazole spin transition coordination polymers for which a modification of anion and crystallization solvent can tune the switching temperature over a wide range, including the room temperature region, is reported. This series of materials was prepared ...

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Spheroid Metallacycles and Metallocavitands with Calixarene- and/or Cleft-Shaped Receptors on the Surface

21.04.2016 | Bhaskaran Shankar; Rajendiran Marimuthu; Shankar Deval Sathiyashivan; Malaichamy Sathiyendiran, Inorganic Chemistry, 2016

Flexible hexatopic ligands, 1,2,3,4,5,6-hexakis(1H-naphtho[2,3-d]imidazol-1-ylmethyl)benzene (L2) and 1,2,3,4,5,6-hexakis(4,5-diphenylimidazol-1-ylmethyl)benzene (L3), containing six neutral naphthanoimidazolyl and 4,5-diphenylimidazolyl N donors were synthesized and used to assemble M6L6L′-type ...

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Solvent-Induced Single Crystal–Single Crystal Transformation of an Interpenetrated Three-Dimensional Copper Triazole Catalytic Framework

21.04.2016 | Ying Wang; Shan-Shan Meng; Peng-Xiang Lin; Yi-Wei Xiao; Qing-Qing Ma; Qiong Xie; Yuan-Yuan Chen; Xiao-Jun Zhao; Jun Chen, Inorganic Chemistry, 2016

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.6b00433

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Regioselective Synthesis and Crystallographic Characterization of Isoxazoline-Ring-Fused Derivatives of Sc3N@Ih-C80 and C60

21.04.2016 | Lipiao Bao; Muqing Chen; Wangqiang Shen; Changwang Pan; Kamran B. Ghiassi; Marilyn M. Olmstead; Alan L. Balch; Takes ..., Inorganic Chemistry, 2016

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.6b00631

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DNA Photocleavage by Non-innocent Ligand-Based Ru(II) Complexes

21.04.2016 | Yangyang Zhang; Qianxiong Zhou; Yue Zheng; Ke Li; Guoyu Jiang; Yuanjun Hou; Baowen Zhang; Xuesong Wang, Inorganic Chemistry, 2016

In this work, we demonstrate for the first time that [Ru(bpy)2(R-OQN)]+ complexes (bpy = 2,2′-bipyridine, R-OQN = 5-chloro-8-oxyquinolate or 5-bromo-8-oxyquinolate) are able to generate hydroxyl radicals and cleave DNA effectively upon visible light irradiation. The potent electron-donating ...

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Common Building Motifs in Ba2Fe3(PO4)4·2H2O, BaFe3(PO4)3, and Na3Fe3(PO4)4: Labile Fe2+/Fe3+ Ordering and Charge-Dependent Magnetism

20.04.2016 | Rénald David; Alain Pautrat; Houria Kabbour; Olivier Mentré, Inorganic Chemistry, 2016

Two new mixed-valence Fe2/3+ barium phosphates have been synthesized in hydrothermal conditions and characterized: Ba2Fe2.66+3(PO4)4·2H2O (compound 1, ratio Fe3+/Fe2+ = 2:1, orthorhombic space group Pbca, a = 6.71240(10) Å, b = 10.6077(2) Å, c = 20.9975(5) Å, R1 = 3.39%) and BaFe2.33+3(PO4)3 ...

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X-ray Absorption and Emission Spectroscopic Studies of [L2Fe2S2]n Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron–Sulfur Clusters

20.04.2016 | Joanna K. Kowalska; Anselm W. Hahn; Antonia Albers; Christine E. Schiewer; Ragnar Bjornsson; Frederico A. Lima; Fran ..., Inorganic Chemistry, 2016

Herein, a systematic study of [L2Fe2S2]n model complexes (where L = bis(benzimidazolato) and n = 2-, 3-, 4-) has been carried out using iron and sulfur K-edge X-ray absorption (XAS) and iron Kβ and valence-to-core X-ray emission spectroscopies (XES). These data are used as a test set to evaluate ...

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The Complexation of Cm(III) with Succinate Studied by Time-Resolved Laser Fluorescence Spectroscopy and Quantum Chemical Calculations

20.04.2016 | Daniel R. Fröhlich; Michael Trumm; Andrej Skerencak-Frech; Petra J. Panak, Inorganic Chemistry, 2016

The complexation of Cm(III) with succinate in an aqueous NaCl solution was studied as a function of ionic strength, ligand concentration, and temperature using time-resolved laser fluorescence spectroscopy (TRLFS). After the Cm(III) speciation was determined by peak deconvolution, the ...

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An Undecanuclear Ferrimagnetic Cu9Dy2 Single Molecule Magnet Achieved through Ligand Fine-Tuning

20.04.2016 | Irina A. Kühne; George E. Kostakis; Christopher E. Anson; Annie K. Powell, Inorganic Chemistry, 2016

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.6b00490

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1D to 3D and Chiral to Noncentrosymmetric Metal–Organic Complexes Controlled by the Amount of DEF Solvent: Photoluminescent and NLO Properties

19.04.2016 | Yuehong Wen; Tianlu Sheng; Chao Zhuo; Xiaoquan Zhu; Shengmin Hu; Wenhai Cao; Haoran Li; Hao Zhang; Xintao Wu, Inorganic Chemistry, 2016

A mixture of 2D and 1D metal–organic complexes, [ZnL(H2O)2·G1·DEF·2H2O]n (1a: G1 = naphthalene-2,7-disulfonate; DEF = N,N-diethylformamide) and [ZnL(H2O)3·G1·DEF·2H2O]n (2), has been prepared from a hydrogenated Schiff base L and Zn(II) in a DEF-contained solvent system under mild conditions. The ...

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