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9.680 Aktuelle Fachpublikationen in Inorganic Chemistry


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Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties

19.10.2017 | Alexey N. Bilyachenko; Alexey Yalymov; Marina Dronova; Alexander A. Korlyukov; Anna V. Vologzhanina; Marina A. Es’ko ..., Inorganic Chemistry, 2017

A new family of bi-, tetra-, penta-, and hexanickel cagelike phenylsilsesquioxanes 1–6 was obtained by self-assembly and transmetalation procedures. Their crystal structures were established by single-crystal X-ray analysis, and features of crystal packing relevant to the network formation were ...


Cleavage of Hg–C Bonds of Organomercurials Induced by ImOHSe via Two Distinct Pathways

12.10.2017 | Mainak Banerjee; Gouriprasanna Roy, Inorganic Chemistry, 2017

We show that the N-methylimidazole-based selone ImOHSe having an N–CH2CH2OH substituent has the remarkable ability to degrade methylmercury by two distinct pathways. Under basic conditions, ImOHSe converts MeHgCl into biologically inert HgSe nanoparticles and Me2Hg via the formation of an ...


Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling

09.10.2017 | James T. Brewster II; Gonzalo Anguera; Matthew D. Moore; Brian S. Dolinar; Hadiqa Zafar; Grégory D. Thiabaud; Vincen ..., Inorganic Chemistry, 2017

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b01669


Eminently Enhanced Anticorrosion Performance and Mechanisms of X-ZnO (X = C, N, and P) Solid Solutions

05.10.2017 | Jing-Yu Zhang; Xi-Zi Xue; Jin-Ku Liu, Inorganic Chemistry, 2017

Nonmetal (C, N, P) doped zinc oxide solid solutions (ZnO SSs) prepared through one-step calcination method exhibited novel anticorrosion capability. The anticorrosion property was identified by electrochemical impedance spectroscopy and polarization curve technique. The maximal impedance belonged ...


Binding of Mono- and Dianions within Silver Thiazolylurea Tweezers and Capsules

05.10.2017 | Novia T. X. Lee; Jamie Hicks; Karl J. Wallace; David R. Turner, Inorganic Chemistry, 2017

A silver thiazolylurea complex, [Ag(TUTh)2]+, has been used as a host species for geometrically differently shaped mono- and dianions: trigonal planar (NO3–), tetrahedral (SO42–), and octahedral (SiF62–). In the presence of nitrate a 1:1 near-planar tweezer host–guest species is formed, with poor ...


The Effect of Sr2+ on Luminescence of Ce3+-Doped (Ca,Sr)2Al2SiO7

27.09.2017 | Litian Lin; Rui Shi; Rongfu Zhou; Qi Peng; Chunmeng Liu; Ye Tao; Yan Huang; Pieter Dorenbos; Hongbin Liang, Inorganic Chemistry, 2017

A series of Ce3+-doped (Ca,Sr)2Al2SiO7 phosphors with different Ce3+ and Ca2+/Sr2+ concentrations were prepared by a high temperature solid-state reaction technique. To get insight into the structure–luminescence relationship, the impact of incorporation of Sr2+ on structure of (Ca,Sr)2Al2SiO7 ...


ICT–Isomerization-Induced Turn-On Fluorescence Probe with a Large Emission Shift for Mercury Ion: Application in Combinational Molecular Logic

19.09.2017 | Sushil Ranjan Bhatta; Bijan Mondal; Gonela Vijaykumar; Arunabha Thakur, Inorganic Chemistry, 2017

A unique turn-on fluorescent device based on a ferrocene–aminonaphtholate derivative specific for Hg2+ cation was developed. Upon binding with Hg2+ ion, the probe shows a dramatic fluorescence enhancement (the fluorescence quantum yield increases 58-fold) along with a large red shift of 68 nm in ...


Syntheses and Properties of Gold–Organotin Sulfide Clusters

01.09.2017 | Eike Dornsiepen; Jens P. Eußner; Nils W. Rosemann; Sangam Chatterjee; Stefanie Dehnen, Inorganic Chemistry, 2017

We report that reactions of the binary organotin sulfide cluster [(R1Sn)3S4]Cl [A; R1 = CMe2CH2C(O)Me] with gold(I) phosphane complexes yield discrete ternary complexes [(R1Sn)2(AuPMe3)2S4] (1) and [(R2Sn)2(AuPMe3)2S4] [2; R2 = CMe2CH2C(NNH2)Me], which are related to recently published complexes ...


A Luminescent 3d-4f-4d MOF Nanoprobe as a Diagnosis Platform for Human Occupational Exposure to Vinyl Chloride Carcinogen

01.09.2017 | Ji-Na Hao; Xiao-Yu Xu; Xiao Lian; Chi Zhang; Bing Yan, Inorganic Chemistry, 2017

A luminescent nanoprobe based on a lanthanide-transition heterometallic metal–organic framework (MOF) is first designed for specific detection of urinary thiodiglycolic acid (TDGA) which is the biomarker of carcinogenic vinyl chloride monomer (VCM) and represents the internal dose of human ...


Role of Ligand Protonation in Dihydrogen Evolution from a Pentamethylcyclopentadienyl Rhodium Catalyst

01.09.2017 | Samantha I. Johnson; Harry B. Gray; James D. Blakemore; William A. Goddard, III, Inorganic Chemistry, 2017

Recent work has shown that Cp*Rh(bpy) [Cp* = pentamethylcyclopentadienyl, bpy = 2,2′- bipyridine] undergoes endo protonation at the [Cp*] ligand in the presence of weak acid (Et3NH+; pKa = 18.8 in MeCN). Upon exposure to stronger acid (e.g., DMFH+; pKa = 6.1), hydrogen is evolved with unity ...


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