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1.132 Aktuelle Fachpublikationen zum Thema Addition

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Oxidative Addition of Dialkyldichalcogenanes to a Cyclic Bis(amino)germylene – Germane vs. Digermane Formation

21.10.2014 | Phillip Steiniger; Georg Bendt; Dieter Bläser; Christoph Wölper; Stephan Schulz, Chemical Communication, 2014

Chem. Commun., 2014, Accepted ManuscriptDOI: 10.1039/C4CC07921C, Communication Phillip Steiniger, Georg Bendt, Dieter Blaser, Christoph Wolper, Stephan SchulzThis is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. ...

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Synthesis and Ligand Modification Chemistry of a Molybdenum Dinitrogen Complex: Redox and Chemical Activity of a Bis(imino)pyridine Ligand

16.10.2014 | Grant W. Margulieux, Zoë R. Turner, Paul J. Chirik, Angewandte Chemie International Edition, 2014

Abstract The bis(imino)pyridine 2,6‐(2,6‐iPr2‐C6H3NCPh)2‐C5H3N (iPrBPDI) molybdenum dinitrogen complex, [{(iPrBPDI)Mo(N2)}2(μ2,η1,η1‐N2)] has been prepared and contains both weakly (terminal) and modestly (bridging) activated N2 ligands. Addition of ammonia resulted in sequential NH bond ...

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Photoemission investigation of the Schottky barrier at the Sc/3C‐SiC (111) interface

16.10.2014 | Sean W. King, Robert J. Nemanich, Robert F. Davis, physica status solidi (b), 2014

The Schottky barrier and interfacial chemistry for interfaces formed by evaporation of Sc onto 3C‐SiC (111)‐(1x1) surfaces at 600 °C has been investigated using in situ X‐ray and ultra‐violet photoelectron spectroscopy (XPS and UPS) and low energy electron diffraction (LEED). Sc was observed to ...

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Formation of C–X Bonds through Stable Low-Electron-Count Cationic Platinum(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes

14.10.2014 | Orestes Rivada-Wheelaghan; Marta Roselló-Merino; Josefina Díez; Celia Maya; Joaquín López-Serrano; Salvador Conejero, Organometallics, 2014

Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling reactions and most particularly in Shilov-type chemistry. The alkyl ...

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Toughening Polylactide with Phase‐Separating Complex Copolymer Architectures

13.10.2014 | William M. Gramlich, Macromolecular Chemistry and Physics, 2014

Polylactide (PLA) is a commercially produced potentially sustainable plastic that holds promise to replace petroleum‐sourced materials. Unfortunately, the brittle nature of PLA limits its current utility to disposable packaging. Melt blends of PLA and a rubbery material can rubber toughen the ...

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Towards to the improvement of the analytical response in voltammetric sensors based on rigid composites

12.10.2014 | Author(s): R. Montes , J. Bartrolí , F. Céspedes , M. Baeza, Journal of Electroanalytical Chemistry, 2014

Publication date: 1 November 2014 Source:Journal of Electroanalytical Chemistry, Volume 733 Author(s): R. Montes , J. Bartrolí , F. Céspedes , M. Baeza In order to increase the efficiency of voltammetric transducers we have studied the use of alternative strategies to characterize and ...

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Voltammetric determination of ropinirole in the presence of levodopa at the surface of a carbon nanotubes based electrochemical sensor in pharmaceuticals and human serum

12.10.2014 | Author(s): Mirela Sadiković , Biljana Nigović , Sandra Jurić , Ana Mornar, Journal of Electroanalytical Chemistry, 2014

Publication date: 1 November 2014 Source:Journal of Electroanalytical Chemistry, Volume 733 Author(s): Mirela Sadiković , Biljana Nigović , Sandra Jurić , Ana Mornar A nanostructured electrochemical sensor was developed to establish an innovative way to measure ropinirole and levodopa ...

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Nanohybrids of quantum dots and cytochrome P450 for light-driven drug metabolism

12.10.2014 | Author(s): Jing Qian , Wei Zhu , Li Mi , Xuan Xu , Jiachao Yu , Dongmei Cui , Yanchun Xue , Songqin Liu, Journal of Electroanalytical Chemistry, 2014

Publication date: 1 November 2014 Source:Journal of Electroanalytical Chemistry, Volume 733 Author(s): Jing Qian , Wei Zhu , Li Mi , Xuan Xu , Jiachao Yu , Dongmei Cui , Yanchun Xue , Songqin Liu In this work, nanohybrids of CdTe quantum dots (QDs) and cytochrome P450 2D6 (CYP2D6) ...

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DSSCs synergic effect in thin metal oxide layer-functionalized SnO2 photoanodes

12.10.2014 | Author(s): Sambhaji S. Bhande , Dipak V. Shinde , Kailas K. Tehare , Supriya A. Patil , Rajaram S. Mane , Mu. ..., Journal of Photochemistry and Photobiology A: Chemistry, 2014

Publication date: 1 December 2014 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volume 295 Author(s): Sambhaji S. Bhande , Dipak V. Shinde , Kailas K. Tehare , Supriya A. Patil , Rajaram S. Mane , Mu. Naushad , Z.A Alothman , K.N. Hui , Sung Hwan Han DSSCs ...

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Palladium(II) and Platinum(II) Complexes Containing Six‐Membered N‐Heterocyclic Ligands: Synthesis, Characterization, Interaction with DNA, DFT Calculation, and Cytotoxicity

10.10.2014 | Ya‐guang Sun, Ying Guo, Di Sun, Ming‐chang Zhu, Fu Ding, Yi‐nan Liu, En‐jun Gao, Shu‐ju Wang, Gang Xiong, Ileana Dra ..., European Journal of Inorganic Chemistry, 2014

Abstract Four novel complexes based on the ligand piperazine (Pip) in a chair conformation have been synthesized, namely [Pd(5,5′‐dcbpy)Pip]·4H2O (1), [Pt(5,5′‐dcbpy)Pip]·3H2O (2), [Pd(4,4′‐dcbpy)Pip]·4H2O (3), and [Pt(4,4′‐dcbpy)Pip]·2H2O (4; 4,4′‐dcbpy = 2,2′‐bipyridyl‐4,4′‐dicarboxylate, ...

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