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47.614 Aktuelle Fachpublikationen zum Thema temperature

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Neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

27.08.2015 | Yuan-Yuan Ren; Nai-Wei Wu; Junhai Huang; Zheng Xu; Dan-Dan Sun; Cui-Hong Wang; Lin Xu, Chemical Communication, 2015

A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulited by temperature or F-, the reversible gel-sol transition was realized. More interestingly, TPA ...


Hexagonal Columnar Liquid Crystal as a Processing Additive to P3HT: PCBM Photoactive Layer

27.08.2015 | Ahipa T.N; Anoop K M; Dr. Ranjith Krishna Pai, New Journal of Chemistry, 2015

Morphology of the donor/acceptor network in the photoactive layer is critical in order to optimize the device performance. In the present study, new trihydrazone-functionalized cyanopyridine (CPTH-D16) demonstrating ambient temperature hexagonal columnar liquid crystalline phase is introduced ...


Synthesis of BiOI/Bi4O5I2/Bi2O2CO3 p-n-p heterojunctions with superior photocatalytic activities

26.08.2015 | An-Wu Xu; yin peng; pianpian yu; hai yan zhou, New Journal of Chemistry, 2015

One-dimensional (1D) BiOI/Bi4O5I2/Bi2O2CO3 p-n-p heterojunction photocatalyst was synthesized by low-temperature solution method using Bi2O3 nanorods as sacrificial template. The formation mechanism of BiOI/Bi4O5I2/Bi2O2CO3heterostructure was discussed in detail according to the results of IR, ...


The luminescence properties of heteroleptic [OsCl(CO)(N[intersection]N)(P[intersection]P)]+ complexes - radiative and non-radiative deactivation of the excited 3*MLCT state

26.08.2015 | Anna Kamecka; Andrzej Kapturkiewicz, Physical Chemistry Chemical Physics, 2015

The luminescence properties of the heteroleptic [OsCl(CO)(N∩N)(P∩P)]+ complexes with bidentate phosphine P∩P and diimine N∩N ligands have been studied in acetonitrile solutions at room temperature and in methanol/ethanol (1 [ ] : [ ] 1) glasses at 77 K. At room temperature the investigated ...


In situ synchrotron XRD investigation of the dehydration and high temperature carbonation of Ca(OH)2

26.08.2015 | Vlatko Materic; Bridget Ingham; Robert Holt, CrystEngComm, 2015

The dehydration and high temperature carbonation reactions of Ca(OH)2 are an essential part of a number of existing schemes aiming to apply the thermochemical CaO-CaCO3 cycle (‘Ca Looping’) in emerging energy industries such as CO2 capture, gasification and thermal energy storage. However, the ...


Nonaqueous Redox-Flow Batteries: Organic Solvents, Supporting Electrolytes, and Redox Pairs

26.08.2015 | Ke Gong; Qianrong Fang; Shuang Gu; S F Y Li; Yushan Yan, Energy & Environmental Science, 2015

As a family member of redox-flow batteries (RFBs), nonaqueous RFBs can offer wide working temperature, high cell voltage, and potentially high energy density. These key features make nonaqueous RFBs an important complement of aqueous RFBs, broadening the spectrum of RFB applications. The ...


Hydrophobicity: Effect of density & order on water’s rotational slowing down

26.08.2015 | John Tatini Titantah; Mikko Karttunen, Soft Matter, 2015

Ab initio Molecular Dynamics (AIMD) simulations of over 4.5 ns were performed in the temperature range of T=260 K-350 K with van der Waals corrections to investigate the relationship between local water density and tetrahedral order in bulk water and in the presence of a hydrophobe, ...


Structure, luminescence properties and energy transfer of Tb3+-Eu3+ codoped LiBaB9O15 phosphors

26.08.2015 | Ting Li; Panlai Li; Zhijun Wang; Shuchao Xu; Qiongyu Bai; Zhiping Yang, Dalton Transactions, 2015

A series of single-composition phosphors LiBaB9O15:Tb3+, Eu3+ have been prepared via a high-temperature solid-state reaction process. The structure and luminescence properties of phosphors are described. LiBaB9O15:Tb3+ phosphor shows the characteristic green emission, and the peak locates at 551 ...


Cationic Polymer Chain Tethered on the Pore-wall of 3-D Ordered Macroporous Resin for the Removal of Hexavalent Chromium from Aqueous Solution

23.08.2015 | Author(s): Xiaomei Wang, Cuihong Wu, Lei Tian, Guohui Li, Xu Zhang, Feng Lei, Jiayan Qu, Pange Liu, Reactive and Functional Polymers, 2015

Publication date: Available online 18 August 2015 Source:Reactive and Functional Polymers Author(s): Xiaomei Wang, Cuihong Wu, Lei Tian, Guohui Li, Xu Zhang, Feng Lei, Jiayan Qu, Pange Liu A novel 3-D ordered macroporous (3DOM) adsorbent with a cationic polymer chain ...


Role of Substituents on the Reactivity and Product Selectivity in Reactions of Naphthalene Derivatives Catalyzed by the Orphan Thermostable Cytochrome P450, CYP175A1

23.08.2015 | Author(s): Shibdas Banerjee, Sandeep Goyal, Shyamalava Mazumdar, Bioorganic Chemistry, 2015

Publication date: Available online 19 August 2015 Source:Bioorganic Chemistry Author(s): Shibdas Banerjee, Sandeep Goyal, Shyamalava Mazumdar The theromostable nature of CYP175A1 enzyme is of potential interest for the biocatalysis at ambient temperature or at elevated temperature ...


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