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Artificial biomembranes stabilized over spin coated hydrogel scaffolds. Crosslinking agent nature induces wrinkled or flat surfaces on the hydrogel.

07.02.2016 | Author(s): C.M. González-Henríquez, G.C. Pizarro-Guerra, E.N. Córdova-Alarcón, M.A. Sarabia-Vallejos, C.A. ..., Chemistry and Physics of Lipids, 2016

Publication date: Available online 6 February 2016 Source:Chemistry and Physics of Lipids Author(s): C.M. González-Henríquez, G.C. Pizarro-Guerra, E.N. Córdova-Alarcón, M.A. Sarabia-Vallejos, C.A. Terraza-Inostroza Hydrogel films possess the ability of retain water and deliver it ...


IJMS, Vol. 17, Pages 210: Microwave-Assisted Synthesis of Glycoconjugates by Transgalactosylation with Recombinant Thermostable β-Glycosidase from Pyrococcus

04.02.2016 | Henze, Manja ; Merker, Dorothee ; Elling, Lothar, International Journal of Molecular Sciences, 2016

The potential of the hyperthermophilic β-glycosidase from Pyrococcus woesei (DSM 3773) for the synthesis of glycosides under microwave irradiation (MWI) at low temperatures was investigated. Transgalactosylation reactions with β-N-acetyl-d-glucosamine as acceptor substrate (GlcNAc-linker-tBoc) ...


Mechanically Drawable Thermochromic and Mechanothermochromic Polydiacetylene Sensors

03.02.2016 | Songa Chae, Jong Pil Lee, Jong‐Man Kim, Advanced Functional Materials, 2016

Recently, the development of directly writable techniques for depositing functional materials on solid substrates has received great attention. These pen‐on‐paper approaches enable generation of diverse patterned images on solid substrates in a flexible, easy handling, and inexpensive manner. ...


Anomalous Freezing of Nano‐confined Water in Room Temperature Ionic Liquid, 1‐Butyl‐3‐Methylimidazolium Nitrate

03.02.2016 | Hiroshi Abe, Takahiro Takekiyo, Yukihiro Yoshimura, Koji Saihara, Akio Shimizu, ChemPhysChem, 2016

Non‐crystal formation of ice was investigated by simultaneous X‐ray diffraction and differential scanning calorimetry measurements upon cooling to ‐100 °C. At room temperature, size‐tunable water confinement (~20 Å size) in a room temperature ionic liquid (RTIL) exists at water‐rich region (70 ‐ ...


The Reactivity of Diphenyllead(IV) Dichloride with Dissymmetric Thiosemicarbazone Ligands: Obtaining Monomers, Coordination Polymers, and an Organoplumboxane

01.02.2016 | Ester Sesmero, David G. Calatayud, Josefina Perles, Elena López‐Torres, M. Antonia Mendiola, European Journal of Inorganic Chemistry, 2016

Abstract The reaction of PbPh2Cl2 with two dissymmetric thiosemicarbazone ligands containing diacetyl 4‐methyl‐3‐thiosemicarbazone and hydrazonepyridine or hydrazonequinoline arms led to four new mononuclear complexes, [PbPh2(L)] (1 and 3) and [PbPh2Cl(HL)] (2 and 4). Reactions with the ...


Bipyridinium‐bis(carboxylate) Radical Based Materials: X‐ray, EPR and Paramagnetic Solid‐State NMR Investigations

29.01.2016 | Oksana Toma, Maxime Leroux, Nicolas Mercier, Magali Allain, Abdel Hadi Kassiba, Shashi Kumar Kumara Swamy, Jens Dittmer, European Journal of Inorganic Chemistry, 2016

Abstract The zwitterionic 1,1′‐bis(4‐carboxyphenyl)‐4,4′‐bipyridinium (bp4pc) has been synthesized and crystals of its hydrated form bp4pc·2H2O and of its protonated reduced form H‐bp4pc have been obtained. Upon heating, bp4pc·2H2O undergoes partial dehydration, leading to bp4pc·H2O at 160 °C, ...


Swelling behavior of coal in solvent at elevated temperature and pressure and non‐isothermal kinetic analysis

29.01.2016 | Lei Chen, Longtao Zhao, Yi. Cao, Yanxun Li, Hekun Lv, Hao Zhang, Asia-Pacific Journal of Chemical Engineering, 2016

Abstract The swelling ratio of a packed coal bed in a coal liquefaction process derived recycle solvent (REC) and pure tetralin (THN) at elevated temperature and pressure is obtained by a so‐called linear variable differential transformer (LVDT) deformation transducer apparatus. Effects of ...


Isoflavone Profiles and Kinetic Changes during Ultra‐High Temperature Processing of Soymilk

28.01.2016 | Yan Zhang, Sam K.C. Chang, Journal of Food Science, 2016

Abstract Isoflavone profile is greatly affected by heating process. However, kinetic analyses of isoflavone conversion and degradation using a continuous industry processing method have never been characterized. In this study, Proto soybean was soaked and blanched at 80 °C for 2 min and then ...


Small‐Scale Thermal Studies of Volatile Homemade Explosives

26.01.2016 | Mary M. Sandstrom, Geoffrey W. Brown, Kirstin F. Warner, Daniel N. Sorensen, Jason J. Phillips, Timothy J. Shelley, ..., Propellants, Explosives, Pyrotechnics, 2016

Abstract Several homemade or improvised explosive mixtures that either contained volatile components or produced volatile products were examined using standard small‐scale safety and thermal (SSST) testing that employed differential scanning calorimetry (DSC) techniques (constant heating rate ...


Scaffolded Thermally Remendable Hybrid Polymer Networks

25.01.2016 | Gayla Berg Lyon, Austin Baranek, Christopher N. Bowman, Advanced Functional Materials, 2016

Step‐growth Diels–Alder (DA) networks using furan and maleimide groups are particularly useful in forming thermally remendable crosslinked polymers, due to the dramatic shift in equilibrium over a relatively low temperature range as compared with other diene‐dienophile pairs. However, the ...


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