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4.346 Aktuelle Fachpublikationen zum Thema temperature

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Carbohydrate and Lignin are Simultaneously Solubilized from Unpretreated Switchgrass by Microbial Action at High Temperature

22.05.2013 | Ira Kataeva; Marcus B Foston; Sung-Jae Yang; Sivakumar Pattathil; Ajaya K Biswal; Farris L Poole; Mirko Basen; Amand ..., Energy & Environmental Science, 2013

The three major components of plant biomass, cellulose, hemicellulose and lignin, are highly recalcitrant and deconstruction involves thermal and chemical pretreatment. Microbial conversion is a possible solution, but few anaerobic microbes utilize both cellulose and hemicellulose and none ...

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Structural Properties of Trans Hydrido-Hydroxo M(H)(OH)(NH2CMe2CMe2NH2)(PPh3)2 (M =Ru, Os) Complexes and their Proton Exchange Behaviour with Water in Solution

22.05.2013 | R H Morris; Demyan E Prokopchuk; Alan Lough; Alba Collado, Dalton Transactions, 2013

We report the synthesis of Ru(II) and Os(II) trans hydrido-hydroxo complexes by reacting the unsaturated amido complexes MH(NHCMe2CMe2NH2)(PPh3)2 (M = Ru, Os) with stoichiometric amounts of water. Proton exchange is rapid at room temperature between the amine/water/hydroxide moieties which ...

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Improved speed of hydrogen detection by Schottky diodes on InP with electrophoretically deposited Pt nanoparticles and graphite contacts

20.05.2013 | Author(s): Karel Zdansky , James H. Dickerson, Sensors and Actuators B: Chemical, 2013

Publication date: 31 July 2013 Source:Sensors and Actuators B: Chemical, Volume 184 Author(s): Karel Zdansky , James H. Dickerson The electrophoretic deposition (EPD) of nanoparticles (NPs) of the catalytic metal platinum (Pt) onto semiconductor wafers of indium phosphide (InP) from ...

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LCST Phase Separation and Thermoreversible Gelation in Aqueous Solutions of Stereo-Controlled Poly(N-isopropylacrylamide)s

20.05.2013 | Author(s): Fumihiko Tanaka , Yukiteru Katsumoto , Shinya Nakano , Rio Kita, Reactive and Functional Polymers, 2013

Publication date: Available online 14 May 2013 Source:Reactive and Functional Polymers Author(s): Fumihiko Tanaka , Yukiteru Katsumoto , Shinya Nakano , Rio Kita Stereoregular poly(N-isopropylacrylamide)s with controlled content of isotactic dyads have recently been synthesized, and ...

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Modeling of Water Loss during Osmotic Dehydration of Apple Cubes in Sugar Beet Molasses

17.05.2013 | Gordana Koprivica, Nevena Mišljenović, Oskar Bera, Ljubinko Lević, Journal of Food Processing and Preservation, 2013

Abstract Application of the Peleg model was investigated for predicting water loss (WL) during osmotic dehydration of apples in sugar beet molasses at different concentrations (40–80 °Bx) and temperatures (45–65C). Analyses of variance was used in order to find significant effects of ...

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Synthesis and self‐assembling of poly(N‐isopropylacrylamide‐block‐poly(L‐lactide)‐block‐poly(N‐isopropylacrylamide) triblock copolymers prepared by combination of ring‐opening polymerization and atom transfer radical polymerization

17.05.2013 | Yanfei Hu, Vincent Darcos, Sophie Monge, Suming Li, Journal of Polymer Science Part A: Polymer Chemistry, 2013

ABSTRACT Novel thermo‐responsive poly(N‐isopropylacrylamide)‐block‐poly(l‐lactide)‐block‐poly(N‐isopropylacylamide) (PNIPAAm‐b‐PLLA‐b‐PNIPAAm) triblock copolymers were successfully prepared by atom transfer radical polymerization of NIPAAm with Br‐PLLA‐Br macroinitiator, using a ...

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IJMS, Vol. 14, Pages 10383-10396: Influence of Growth Conditions on Magnetite Nanoparticles Electro-Crystallized in the Presence of Organic Molecules

17.05.2013 | Mosivand, Saba ; Monzon, Lorena M. A.; Kazeminezhad, Iraj ; Coey, J. Michael D., International Journal of Molecular Sciences, 2013

Magnetite nanoparticles were synthesized by electrocrystallization in the presence of thiourea or sodium butanoate as an organic stabilizer. The synthesis was performed in a thermostatic electrochemical cell containing two iron electrodes with an aqueous solution of sodium sulfate as ...

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Interpreting “Acidity” as a Global Property Controlling Comonomer Reactivity in Olefin Polymerization

17.05.2013 | Lorella Izzo; Massimo Mella, Organometallics, 2013

A possible rationale for the different catalytic behaviors of systems based on rac-(ethylenebis(1-indenyl))zirconium dichloride (rac-EBIZrCl2), rac-(ethylenebis(1-indenyl))hafnium dichloride (rac-EBIHfCl2), and rac-(isopropylidenebis(1-indenyl))zirconium dichloride (rac-iPrBIZrCl2) toward ...

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Effect of Citric Acid and Starch as Emulsifier on Phase Formation and Crystallite Size of Lanthanum Oxide Nanoparticles

16.05.2013 | Hamidreza Bojari, Azim Malekzadeh, Mahnaz Ghiasi, Ahmad Gholizadeh, Ramin Azargohar, Ajay Kumar Dalai, Crystal Research and Technology, 2013

Lanthanum oxide nanoparticles were synthesized via thermal decomposition method of the lanthanum nitrate in the presence of citric acid or starch as emulsifier. The effects of emulsifier and calcination temperature were investigated on the phase transformation and particle size distribution ...

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Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

15.05.2013 | Holger Braunschweig; Alexander Damme, Chemical Communication, 2013

cis-[(Cy3P)2Pt{B(OMe)2}2] (1) was obtained in quantitative yield and fully characterised. The thermal stability of 1 was investigated in solution using multinuclear NMR spectroscopy revealing a hitherto unknown temperature-dependent equilibrium between 1 and the corresponding starting ...

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