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An air and moisture tolerant iminotrihydroquinoline-ruthenium(II) catalyst for the transfer hydrogenation of ketones

Reaction of 8-amino-5,6,7,8-tetrahydroquinoline with RuCl2(PPh3)3 at room temperature affords the ruthenium(ii) chelate (8-NH2-C9H10N)RuCl2(PPh3)2 (E), in which the two triphenylphosphine ligands are disposed mutually cis. By contrast, when the reaction is performed at reflux ligand oxidation/dehydrogenation occurs

Autoren:   Jiaoyan Li; Yingmiao Ma; Zheng Wang; Qingbin Liu; Gregory A. Solan; Yanping Ma; Wen-Hua Sun
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01919C
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