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Spontaneous resolution of a [capital Delta]/[capital Lambda]-chiral-at-metal pseudo-tetrahedral Schiff-base zinc complex to a racemic conglomerate with C-H[middle dot][middle dot][middle dot]O organized 41- and 43-helices

The Schiff-base ligand, N-2-(pyridyl)salicylaldimine (HL) reacts with zinc(II) acetate or nitrate to give the enantiomorphous chiral-at-metal compound Δ/Λ-bis[N-2-(pyridyl)salicylaldiminato-κ2N,O]zinc(II), [Zn(L)2] (1), which crystallizes as a racemic conglomerate via spontaneous resolution. Two deprotonated

Autoren:   Mohammed Enamullah; Vera Vasylyeva; Mohammed Abdul Quddus; Mohammad Khairul Islam; Simon-Patrick Höfert; Christoph Janiak
Journal:   CrystEngComm
DOI:   10.1039/C8CE00839F
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