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Direct C-OH/P(O)-H Dehydration Coupling Forming Phosphine Oxides

A t-BuONa-mediated C-OH/P(O)-H cross dehydration coupling to produce alkylphosphine oxides is developed. This reaction employed the readily available alcohols and P(O)-H compounds as the starting materials, providing an efficient alternative method for constructing sp3C-P bonds. A reasonable reaction path in Synthetic methodology in OBC

Autoren:   Long Chen; Yueyue Zhu; Tieqiao Chen; Long Liu; Ji-Shu Zhang; Li-Biao Han
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB01299G
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