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Tetranuclear and dinuclear phenoxido bridged copper complexes based on unsymmetrical thiosemicarbazone ligands

We report on the synthesis of new dinucleating phenol-based “end-off” compartmental ligands HLMeH and HLMe2 bearing two different binding sites, one bis(2-methylpyridyl)aminomethyl (BPA) and one thiosemicarbazone (TSC) site, and their corresponding copper(II) complexes 1t and 2d. With the ligand HLMeH, a tet

Autoren:   Catherine Belle; James Alfred Isaac; Ali Taher Mansour; Rolf David; Amelie Kochem; Christian Philouze; Serhiy Demeshko; Franc Meyer; Marius Reglier; A. Jalila Simaan; Stefano Caldarelli; Mehdi Yemloul; Helene Jamet; Aurore Thibon-Pourret
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02452A
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