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Sequential hydrogenation of polycyclic aromatic hydrocarbon (PAH) cations drives a gradual transition from a planar to a puckered geometry and from an aromatic to an aliphatic electronic structure. The resulting H-induced weakening of the molecular structure together with the exothermic nature of the consecutive H-
| Autoren: | Mathias Rapacioli; Stéphanie Cazaux; Nolan Foley; Aude Simon; Ronnie Hoekstra; Thomas Schlathölter | |
| Journal: | Physical Chemistry Chemical Physics | |
| DOI: | 10.1039/C8CP03024C |
Chemical sensing with 2D materials
During the last decade, two-dimensional materials (2DMs) have attracted great attention due to their unique chemical and physical properties, which make them appealing platforms for diverse applications in opto-electronic devices, energy generation and storage, and sensing. Among their vari ... mehr
An intramolecular annulation strategy has been developed for the synthesis of tetrahydrobenzo[e]pyrano[4,3-c][1,2]thiazine derivatives by means of coupling of aldehydes with 2-(4-hydroxybut-1-yn-1-yl)-N-arylsulfonamides using a catalytic amount of silver hexafluoroantimonate in toluene at 8 ... mehr
Effect of copolymer sequence on structure and relaxation times near a nanoparticle surface
We simulate a simple nanocomposite consisting of a single spherical nanoparticle surrounded by coarse-grained polymer chains. The polymers are composed of two different monomer types that differ only in their interaction strengths with the nanoparticle. We examine the effect of adjusting co ... mehr
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