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N-Methyliminodiacetate (MIDA): A Useful Protecting Group for the Generation of Complex Organoboron Compounds

Quentin I. Churches - Volume 64(11)

Organoboron compounds are extremely useful building blocks for organic synthesis; however, they suffer from incompatibilities with many synthetic transformations. A recently reported boron protecting group, the N-methyliminodiacetate (MIDA) boronate complex ,shows good stability and resistance to a wide variety of chemistries including many transition metal catalyzed reactions. The ability to protect and mask the boron functionality has led to an expanded role for boron in the synthesis of complex molecules.

Autoren:   Quentin I. Churches,
Journal:   Australian Journal of Chemistry
Band:   64
Ausgabe:   11
Jahrgang:   2011
Seiten:   1474
DOI:   10.1071/CH11303
Erscheinungsdatum:   16.11.2011
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