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Preparation of RHgCl via transmetalation of (8-quinolyl)SnMe3 and redistribution to R2Hg (R = 8-quinolyl): a highly distorted diorganomercury(II) with 84 degree C–Hg–C angle

Transmetalation occurs upon addition of HgCl2 to (8-quinolyl)SnMe3 to yield (8-quinolyl)HgCl. The molecule features a frustrated Hg–N Lewis pair; however the mercury(ii) center showed low affinity for sulfur Lewis bases, S8 or thiophene. In the presence of NH4SCN, ligand redistribution led to R2Hg. The molecule was

Autoren:   Sem Raj Tamang; Jung-Ho Son; James D. Hoefelmeyer
Journal:   Dalton Transactions
DOI:   10.1039/C4DT00384E
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