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1.308 Aktuelle Fachpublikationen in Applied Organometallic Chemistry

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Current Applications of Suzuki–Miyaura Coupling Reaction in The Total Synthesis of Natural Products: An update

19.01.2018 | Afsaneh Taheri Kal Koshvandi, Majid M. Heravi, Tayebeh Momeni, Applied Organometallic Chemistry, 2018

Suzuki‐Miyaura Coupling Reaction (SMCR) has been extensively used in the total synthesis of natural products. We underscored these achievements in a report published in Tetrahedron up to 2012. Since then, there has been tremendous growth in this field and numerous articles have been published ...

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Synthesis of V5+‐doped Ag/AgCl photocatalysts with enhanced visible light photocatalytic activity

19.01.2018 | Caiping Guo, Limin Song, Yamiao Li, Shujuan Zhang, Applied Organometallic Chemistry, 2018

V5+‐doped Ag/AgCl photocatalysts were prepared via the ion exchange method. The catalysts were characterized using X‐ray diffractometry, transmission electron microscopy, and energy‐dispersive X‐ray, X‐ray photoelectron, Fourier transform infrared and ultraviolet–visible spectroscopies. The ...

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Synthesis and properties of m‐ferrocenylbenzoylthiadiazole derivatives

19.01.2018 | Biao Li, Xinju Zhu, Yuan Guo, Ya‐Ping Ren, Zhao‐Dong Jia, Jing‐Na Wei, Dong‐Xia Fu, Yan Xu, Xin‐Qi Hao, Applied Organometallic Chemistry, 2018

A series of m‐ferrocenylbenzoylthiadiazole compounds, namely FcL1–FcL7, were synthesized using 3‐ferrocenylbenzoic acid and 2‐amino‐5‐aryl‐1,3,4‐thiadiazole as raw materials. These compounds were characterized using infrared and NMR spectroscopies and elemental analysis. The crystal structure of ...

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Synthesis, properties and mechanism of photodegradation of core–shell structured upconversion luminescent NaYF4:Yb3+,Er3+@BiOCl

19.01.2018 | Shiyu Zhou, Qiyan Zhang, Deqiang Zhao, Wenjuan Zong, Zihong Fan, Yaofang Sun, Xuan Xu, Applied Organometallic Chemistry, 2018

Microspherical bismuth oxychloride (BiOCl) can only utilize ultraviolet (UV) light to promote photocatalytic reactions. To overcome this limitation, a uniform and thin BiOCl nanosheet was synthesized with a particle size of about 200nm. As results of UV–visible diffuse reflectance spectroscopy ...

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Selective hydrogenation of aromatic compounds using modified iridium nanoparticles

19.01.2018 | He‐yan Jiang, Jie Xu, Bin Sun, Applied Organometallic Chemistry, 2018

Till now, Ionic liquid‐stabilized metal nanoparticles were investigated as catalytic materials, mostly in the hydrogenation of simple substrates like olefins or arenes. The adjustable hydrogenation products of aromatic compounds, including quinoline and relevant compounds, aromatic nitro ...

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Palladium nanoparticles immobilized on cyclodextrin‐decorated halloysite nanotubes: Efficient heterogeneous catalyst for promoting copper‐ and ligand‐free Sonogashira reaction in water–ethanol mixture

19.01.2018 | Samahe Sadjadi, Applied Organometallic Chemistry, 2018

Combining the excellent features of halloysite nanoclay and cyclodextrin, a novel hybrid system was designed and synthesized based on covalent attachment of tosylated cyclodextrin to thiosemicarbazide‐functionalized halloysite nanoclay and used for the immobilization of Pd nanoparticles. The ...

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Phosphorus‐nitrogen compounds. Part 39. Syntheses and Langmuir‐Blodgett thin films and antimicrobial activities of N/N and N/O spirocyclotriphosphazenes with monoferrocenyl pendant arm

17.01.2018 | Nuran Asmafiliz, Mehmet Civan, Arda Özben, Zeynel Kılıç, Nagehan Ramazanoğlu, Leyla Açık, Tuncer Hökelek, Applied Organometallic Chemistry, 2018

The Cl substitution reactions of the N/N (1‐3) and N/O (4 and 5) spirocyclic monoferrocenylphosphazenes with 1,4‐dioxa‐8‐azaspiro[4,5]decane (DASD) produce the mono‐ (1a‐5a), geminal‐ (1b‐5b) and tetrakis‐DASD‐substituted ferrocenylspirocyclotriphosphazenes (1c‐5c). The mono‐ and ...

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Phosphorus‐nitrogen compounds. Part 39. Syntheses and Langmuir‐Blodgett thin films and antimicrobial activities of N/N and N/O spirocyclotriphosphazenes with monoferrocenyl pendant arm

17.01.2018 | Nuran Asmafiliz, Mehmet Civan, Arda Özben, Zeynel Kılıç, Nagehan Ramazanoğlu, Leyla Açık, Tuncer Hökelek, Applied Organometallic Chemistry, 2018

The Cl substitution reactions of the N/N (1‐3) and N/O (4 and 5) spirocyclic monoferrocenylphosphazenes with 1,4‐dioxa‐8‐azaspiro[4,5]decane (DASD) produce the mono‐ (1a‐5a), geminal‐ (1b‐5b) and tetrakis‐DASD‐substituted ferrocenylspirocyclotriphosphazenes (1c‐5c). The mono‐ and ...

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Preparation and Characterization of Ni‐Modified Graphene Oxide Complex as an Efficient Catalyst for the Synthesis of Sulfides via Reaction of Arylhalides with S8 or Thiourea

17.01.2018 | Raziyeh Ghafouri‐Nejad, Maryam Hajjami, Razieh Nejat, Applied Organometallic Chemistry, 2018

In this work, complex of Ni‐modified graphene oxide was prepared and characterized using FT‐IR spectroscopy, SEM, XRD, TGA and ICP‐OES techniques. This compound used as an efficient and recoverable catalyst for the C–S coupling reaction using sulfur‐transfer reagents (S8 or thiourea). The ...

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Oxazolidine copper complexes: Synthesis, characterization and superoxide dismutase activity of copper(II) complexes with oxazolidine ligands derived from hydroxyquinoline carboxaldehyde

17.01.2018 | Joice Ceolin, Josiéli Demetrio Siqueira, Francisco Mainardi Martins, Paulo C. Piquini, Bernardo A. Iglesias, Davi F. ..., Applied Organometallic Chemistry, 2018

This work describes the synthesis of copper(II) complexes, their identification using spectroscopic and electrochemical methods, structural characterization with X‐ray diffraction and density functional theory calculations (DFT), as well as their catalytic activity mimicking that of superoxide ...

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