03.07.2018 | Joseph Pearson; Marcel Hofstetter; Thomas Dekorsy; Michael Totzeck; Helmut Coelfen, Analyst, 2018

Analytical ultracentrifugation is a powerful technique for analyzing particles in solution, and has proved valuable for a wide range of applications in chemistry, biochemistry and material sciences for many years. The field is presently seeing a resurgence of instrument development from ...

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03.07.2018 | Yushi Bai; Agata Chotera; Olga Taran; Chen Liang; Gonen Ashkenasy; David G. Lynn, Chemical Society Reviews, 2018

Correction for ‘Achieving biopolymer synergy in systems chemistry’ by Yushi Bai et al., Chem. Soc. Rev., 2018, DOI: 10.1039/c8cs00174j.

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03.07.2018 | Jochen Friedrich; Yusen Qiao; Caecilia Maichle-moessmer; Eric J Schelter; Reiner Anwander, Dalton Transactions, 2018

The stabilizing effect of the tris(tert-butoxy)silyoxy ligand on cerium(IV) is revealed by electrochemical and computation methods as well as targeted redox chemistry. Ceric homoleptic complex Ce[OSi(OtBu)3]4 was obtained by the reaction of [Et4N]2[CeCl6] with NaOSi(OtBu)3 at ambient temperature ...

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03.07.2018 | Kosuke Ino; Tomoaki Matsumoto; Noriko Taira; Tatsuki Kumagai; Yuji Nashimoto; Hitoshi Shiku, Lab on a Chip, 2018

Bipolar electrochemistry has attracted great interest for applications based on sensing, electrografting, and electrodeposition, because the technique enables electrochemical reactions to be induced at multiple bipolar electrodes (BPEs) with only a single power supply. However, there are only a ...

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03.07.2018 | Tao Wang; Tiangang Yang; Chunlei Xiao; Zhigang Sun; Donghui Zhang; Xueming Yang; Marissa L. Weichman; Daniel M. Neumark, Chemical Society Reviews, 2018

The transition state is a key concept in the field of chemistry and is important in the study of chemical kinetics and reaction dynamics. Chemical reactions in the gas phase are essentially molecular scattering processes, which are quantum mechanical in nature. Thus probing and understanding ...

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03.07.2018 | Graeme Hogarth; Shishir Ghosh; Shariff Enamul Kabir; Michael G. Richmond; Mohd. Rezaul Haque; Tasneem Siddiquee; V ..., Dalton Transactions, 2018

Mixed-valence dimolybdenum complexes Mo2(O)(CO)2{μ-к2-S(CH2)nS}2(к2-Ph2P(CH2)mPPh2) (n=2,3; m=1,2) (1-4) have been synthesized from one-pot reactions of fac Mo(CO)3(NCMe)3 and dithiols, HS(CH2)nSH, in the presence of diphosphines. The dimolybdenum framework is supported by two thiolate bridges, ...

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03.07.2018 | Roberta Galeazzi; Emiliano Laudadio; Emanuele Falconi; Luca Massaccesi; Luisa Ercolani; Giovanna Mobbili; Cristina ..., Organic & Biomolecular Chemistry, 2018

Glyoxalase II (GlxII) is an antioxidant glutathione-dependent enzyme, which catalyzes the hydrolysis of S-D-lactoylglutathione to form D-lactic acid and glutathione (GSH). The last product is the most important thiol reducing agent present in all eukaryotic cells that have mitochondria and ...

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03.07.2018 | Qi An; Tao Huang; Feng Shi, Chemical Society Reviews, 2018

Correction for ‘Covalent layer-by-layer films: chemistry, design, and multidisciplinary applications’ by Qi An et al., Chem. Soc. Rev., 2018, DOI: 10.1039/c7cs00406k.

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03.07.2018 | Wenwen Huang; Shengjie Ling; Chunmei Li; Fiorenzo G. Omenetto; David L. Kaplan, Chemical Society Reviews, 2018

Silks are natural fibrous protein polymers that are spun by silkworms and spiders. Among silk variants, there has been increasing interest devoted to the silkworm silk of B. mori, due to its availability in large quantities along with its unique material properties. Silk fibroin can be extracted ...

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03.07.2018 | Yin-He Yang; Bin Di; Da-Song Yang, Organic & Biomolecular Chemistry, 2018

A counterintuitive freezing-induced peptide ligation was discovered in the total synthesis of human interferon-ε (hIFN-ε) which blocks HIV infection through unique mechanisms. The successful synthesis of hIFN-ε (187 amino acids) in this research laid the foundation for related anti-AIDS drug ...

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