03.07.2018 | Zhen-Feng Cai; Wei-long Dong; Ting Chen; Huijuan Yan; Dong Wang; Wei Xu; Li-jun Wan, Chemical Communication, 2018

Here we show a conceptual approach to realize the scanning probe based induced-assembly of fullerene (C60) molecules on top of a buffer organic adlayer at room temperature in solution environment. The realization of spatially-defined C60 assembly is attributed to modulation of substrate-molecular ...

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03.07.2018 | Payal Narang; Pannuru Venkatesu, New Journal of Chemistry, 2018

In advance field of pharmaceutical, agricultural and biomedical research, thermoresponsive polymers (TRPs) are potential and candidates which shows their conformational transition at a particular temperature. The conformational transition in TRPs depends on their intermolecular interactions with ...

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03.07.2018 | Jochen Friedrich; Yusen Qiao; Caecilia Maichle-moessmer; Eric J Schelter; Reiner Anwander, Dalton Transactions, 2018

The stabilizing effect of the tris(tert-butoxy)silyoxy ligand on cerium(IV) is revealed by electrochemical and computation methods as well as targeted redox chemistry. Ceric homoleptic complex Ce[OSi(OtBu)3]4 was obtained by the reaction of [Et4N]2[CeCl6] with NaOSi(OtBu)3 at ambient temperature ...

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03.07.2018 | Wenkui Zhang; hongfeng Chen; Yang Xia; Ruyi Fang; Hui Huang; Yongping Gan; Chu Liang; Jun Zhang; Xuesong Liu, New Journal of Chemistry, 2018

MnOx/TiO2 (MnTi) and Nd-modified MnOx/TiO2 (MnNdTi) were prepared via a coprecipitation method. The used samples were obtained by exposing the fresh catalysts to 50 ppm SO2 stream at 210 oC for 3 h and 6 h, respectively. Comparative investigations were performed on the fresh and used catalysts to ...

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03.07.2018 | Danielle Stephanie Konetski; Sudheendran Mavila; Chen Wang; Brady T. Worrell; Christopher N Bowman, Chemical Communication, 2018

Thiol lysolipids undergo thiol-thioester exchange with two phenyl thioester-functionalized tails to produce phospholipid structures that assemble into liposomes with differences in exchange rates, temperature sensitivity, permeability, and continued exchange behavior. This in situ formation ...

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03.07.2018 | Dequan Jiang; Ying Wang; Bingbing Zhang; Guopeng Han; Zhihua Yang; ShiLie Pan, Dalton Transactions, 2018

A new mixed-alkali borate, K11RbB28O48, has been obtained using the high-temperature solution method. It features a new [B28O57] fundamental building block. Meanwhile, these units further polymerize to form unusual triple-layered anionic groups. Thermal analysis, optical property measurement, and ...

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03.07.2018 | Yi XIE; Wenhui Chen; Chao Hu; Tao Zeng; Huirong Jiang; Fen Qiao; Jiani Gu; Xunyi Dong; Xiujian Zhao, CrystEngComm, 2018

Near-infrared plasmonic binary copper-based chalcogenides have found promising applications in photovoltaics and photothermal therapy. Here, we report a facile synthetic protocol for aqueous soluble covellite (CuS) nanocrystals (NCs) at room temperature. In contrast to previously reported routes, ...

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03.07.2018 | Zongquan Bai; Yajun Zheng; Weiwei Han; Yue Ji; Tianlan Yan; Ying Tang; Gang Chen; Zhiping Zhang, CrystEngComm, 2018

A series of micro-sized MgO with various morphologies have been prepared by varying the reaction temperature and stirring time during precipitation, and were investigated for the production of glycerol carbonate from the transesterification of glycerol with dimethyl carbonate. In contrast to ...

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03.07.2018 | Yuanzu Yu; Yan Zhou; Zengqiang Song; Guang Liang, Organic & Biomolecular Chemistry, 2018

A versatile and efficient method for the synthesis of 3-chalcogenyl-indoles from indoles and dichalcogenides employing t-BuOK as a promoter at room temperature has been achieved. The present protocol exhibited a broad functional group tolerance. Diverse 3-sulfenyl- and 3-selenyl-indoles were ...

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03.07.2018 | Michael Rauch; Gerard Parkin, Dalton Transactions, 2018

The tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl magnesium hydride compound, [TismPriBenz]MgH, undergoes insertion of CS2 into the Mg–H bond at room temperature to give [TismPriBenz]Mg(κ2-S2CH), the first structurally characterized magnesium dithioformate compound. The dithioformate ...

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